Citation: LI Jia-Jia, SONG Shuang, MA Dou, QIAO Li, GU Yi, QIAN Feng-Yun, LI Xia. Syntheses, Crystal Structures and Characterization of Binuclear Lanthanide Complexes with 3-Sulfobenzoate and 2-(4-Pyridyl)imidazole[4,5-f]phenanthroline[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 717-724. doi: 10.11862/CJIC.2015.115 shu

Syntheses, Crystal Structures and Characterization of Binuclear Lanthanide Complexes with 3-Sulfobenzoate and 2-(4-Pyridyl)imidazole[4,5-f]phenanthroline

LI Jia-Jia ¹ ,
SONG Shuang ^1,2 ,
MA Dou ¹ ,
QIAO Li ¹ ,
GU Yi ¹ ,
QIAN Feng-Yun ¹ ,
LI Xia ¹

1.
1 Departmentment of Chemistry, Capital Normal University, Beijing 100048, China;
2.
2 National Institute of Occupational Health and Poison Control, Chinese Center for Disease Control and Prevention, Beijing 100050, China

Received Date: 9 October 2014
Available Online: 21 January 2015
Fund Project: 国家自然科学基金(No.21471104)资助项目。 (No.21471104)

Taking 3-sulfobenzoate (3-SBA) and 2-(4-pyridyl)imidazole[4,5-f]phenanthroline (4-PDIP) as the ligands, three lanthanide complexes, [Ln₂(3-SBA)₂(4-PDIP)₂(OH)₂(H₂O)₄]·2H₂O (Ln=Sm (1), Eu (2), Gd (3)) were obtained by hydrothermal method. The crystal structures were determined by single crystal X-ray diffraction. The three complexes are binuclear molecules. In the complexes, two Ln(Ⅲ) ions are linked by two hydroxyl groups in bridging-bidentate coordination mode. 3-SBA and 4-PDIP ligands are coordinated with Ln(Ⅲ) ions by the chelating bidentate coordination mode. The three-dimensional supramolecular structure is formed through the hydrogen bonds between binuclear molecules. Complexes 1 and 3 display intense broad emission bands at 545 nm and 529 nm, respectively, which correspond to the π^*-π transition of the ligands. Complex 2 presents the characteristics emission of Eu(Ⅲ) ion. The narrow emission bands at 579, 592, 612, 650 and 696 nm are attributed to ⁵D₀→⁷F_j (j=0~4) transitions of the Eu(Ⅲ) ion, respectively. CCDC: 1046171, 1; 1046169, 2; 1046170, 3.
- lanthanide complex;3-sulfobenzoate;crystal structure;fluorescence
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