Citation:
JI Wen-Xu, WU Di, YANG Rong, DING Wei-Ping, PENG Lu-Ming. MoO3 Nanobelts/Reduced Graphene Oxide (RGO) Composites as a High-Performance Anode Material for Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry,
;2015, (4): 659-665.
doi:
10.11862/CJIC.2015.111
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MoO3 nanobelts/RGO composites were obtained through a facile and efficient hydrothermal procedure by using organic compound sodium salicylate as both structure-directing agent and reducing agent. The crystal structure, morphologies and electrochemical performances of the as-prepared samples were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, galvanostatic charge/discharge test and electrochemical impedance spectroscopy (EIS). The hybrid material shows a high specific capacity of 1 000 mAh·g-1 with a good cycling stability as an anode material for lithium ion batteries, which has a much enhanced performance compared to bare MoO3 nanobelts.
-
-
-
[1]
[1] Kang B, Ceder G. Nature, 2009,458:190-193
-
[2]
[2] Tarascon J M, Armand M. Nature, 2001,414:359-367
-
[3]
[3] Kang K, Meng Y S, Bréger J, et al. Science, 2006,311:977-980
-
[4]
[4] ZHANG Huan(张欢), QI Lu(其鲁), GAO Xue-Ping(高学平), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(9): 1539-1543
-
[5]
[5] Poizot P, Laruelle S, Grugeon S, et al. Nature, 2000,407:496-499
-
[6]
[6] Taberna P L, Mitra S, Poizot P, et al. Nat. Mater., 2006,5: 567-573
-
[7]
[7] Nam K T, Kim D W, Yoo P J, et al. Science, 2006,312:885-888
-
[8]
[8] Wang B, Chen J S, Wu H B, et al. J. Am. Chem. Soc., 2011, 133:17146-17148
-
[9]
[9] LIU Xiao-Feng(刘晓峰), MI Chang-Huan(米常焕), ZHANG Wen-Qing(张文庆). Chinese J. Inorg. Chem.(无机化学学报), 2014,30(2):242-250
-
[10]
[10] Gao J, Lowe M A, Abruna H D. Chem. Mater., 2011,23:3223-3227
-
[11]
[11] Ji W, Shen R, Yang R, et al. J. Mater. Chem. A, 2014,2:699-704
-
[12]
[12] XUE Hai-Rong(薛海荣), ZHAO Jian-Qing(赵建庆), WANG Tao(王涛), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(8):1601-1608
-
[13]
[13] Zhao G, Zhang N, Sun K. J. Mater. Chem. A, 2013,1:221-224
-
[14]
[14] Hassan M F, Guo Z P, Chen Z, et al. J. Power Sources, 2010,195:2372-2376
-
[15]
[15] Tao T, Glushenkov A M, Zhang C F, et al. J. Mater. Chem., 2011,21:9350-9355
-
[16]
[16] Novoselov K S, Geim A K, Morozov S V, et al. Science, 2004, 306:666-669
-
[17]
[17] Chae H K, Siberio-Perez D Y, Kim J, et al. Nature, 2004,427: 523-527
-
[18]
[18] Zhang Y, Tan Y W, Stormer H L, et al. Nature, 2005,438: 201-204
-
[19]
[19] Mcallister M J, Li J L, Adamson D H, et al. Chem. Mater., 2007,19:4396-4404
-
[20]
[20] Wang H L, Cui L F, Yang Y A, et al. J. Am. Chem. Soc., 2010,132:13978-13980
-
[21]
[21] Zhu X J, Zhu Y W, Murali S, et al. Acs Nano, 2011,5:3333-3338
-
[22]
[22] Zhou G M, Wang D W, Li F, et al. Chem. Mater., 2010,22: 5306-5313
-
[23]
[23] Wu Z S, Ren W C, Wen L, et al. Acs Nano, 2010,4:3187-3194
-
[24]
[24] Paek S M, Yoo E, Honma I. Nano Lett., 2009,9:72-75
-
[25]
[25] Wang D H, Choi D W, Li J, et al. Acs Nano, 2009,3:907-914
-
[26]
[26] Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958,80: 1339-1339
-
[27]
[27] Yang X F, Lu C Y, Qin J L, et al. Mater. Lett., 2011,65: 2341-2344
-
[28]
[28] He H, Klinowski J, Forster M, et al. Chem. Phys. Lett., 1998, 287:53-56
-
[29]
[29] Lerf A, He H, Forster M, et al. J. Phys. Chem. B, 1998,102: 4477-4482
-
[30]
[30] Cai W, Piner R D, Stadermann F J, et al. Science, 2008, 321:1815-1817
-
[31]
[31] Gao W, Alemany L B, Ci L, et al. Nat. Chem., 2009,1:403-408
-
[32]
[32] Mai L Q, Hu B, Chen W, et al. Adv. Mater., 2007,19:3712-3716
-
[33]
[33] Guo X, Fan Q, Yu L, et al. J. Mater. Chem. A, 2013,1:11534-11538
-
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