Citation: WANG Peng, CHEN Shang-Xing, HUANG Min, ZHAO Zhen-Dong, WANG Zong-De, FAN Guo-Rong. Synthesis of Ordered Supermicroporous Silica Using Rosin-Based Quaternary Ammonium Salt[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 767-773. doi: 10.11862/CJIC.2015.105 shu

Synthesis of Ordered Supermicroporous Silica Using Rosin-Based Quaternary Ammonium Salt

1.
1 College of Forestry, Jiangxi Agricultural University, Nanchang 330045, China;
2.
2 Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, China

Corresponding author: CHEN Shang-Xing,
Received Date: 5 November 2014
Available Online: 12 January 2015
Fund Project: 教育部博士学科点专项科研基金课题(No.20133603120002)资助项目。 (No.20133603120002)

Ordered hexagonal supermicroporous silica with nanosheet morphology was successfully synthesized using rosin-based quaternary ammonium salt (dehydroabietyltrimethyl ammonium bromine, short for DTAB) as template agent, tetraethyl orthosilicate as silicate source, and ammonia as alkaline medium. XRD, N₂ adsorption-desorption, TEM, and SEM were used to characterize the samples. The results indicated that the dosage amount of template agent, silicate source, alkaline medium, crystallization temperature and stirring time had great effects on the regularity of the pore structure. When the mole ratio of n_SiO₂:n_DTAB:n_NH₃:n_H₂O was 1.0:0.1:11.3:924.0; crystallization temperature was 373 K; stirring time was 24 h, the sample got the hightest regularity. After the calcination, the synthesized material possessed large surface area (1 024 m²·g^-1), high pore volume (0.56 cm³·g^-1) and narrow pore size distribution (centered at about 1.80 nm).
- rosin-based quaternary ammonium salt;supermicroporous;silica
1. [1]
  [1] Corma A. Chem. Rev., 1997,97(6):2373-2420
2. [2]
  [2] Charnay C, Bégu S, Tourné-Péteilh C, et al. Eur. J. Pharm. Biopharm., 2004,57(3):533-540
3. [3]
  [3] Fan J, Yu C, Gao F, et al. Angew. Chem., 2003,115(27): 3254-3258
4. [4]
  [4] Crossland E J, Noel N, Sivaram V, et al. Nature, 2013,495(7440):215-219
5. [5]
  [5] Kresge C, Leonowicz M, Roth W, et al. Nature, 1992,359(6397):710-712
6. [6]
  [6] Beck J, Vartuli J, Roth W, et al. J. Am. Chem. Soc., 1992, 114(27):10834-10843.
7. [7]
  [7] Huo Q, Margolese D I, Stucky G D. Chem. Mater., 1996,8(5):1147-1160
8. [8]
  [8] Yu C, Tian B, Fan J, et al. J. Am. Chem. Soc., 2002,124(17):4556-4557
9. [9]
  [9] Zhao D, Feng J, Huo Q, et al. Science, 1998,279(5350):548-552
10. [10]
  [10] Tanev P T,Pinnavaia T J. Science, 1995,267(5199):865-867
11. [11]
  [11] Bagshaw S A, Prouzet E, Pinnavaia T J. Science, 1995,269(5228):1242-1244
12. [12]
  [12] Yu C, Yu Y, Zhao D. Chem. Commun., 2000(7):575-576
13. [13]
  [13] Liu X, Tian B, Yu C, et al. Angew. Chem. Int. Ed., 2002,41(20):3876-3878
14. [14]
  [14] Fan J, Yu C, Wang L, et al. J. Am. Chem. Soc., 2001,123(48):12113-12114
15. [15]
  [15] Zhou G, Chen Y, Yang J, et al. J. Mater. Chem., 2007,17(27):2839-2844
16. [16]
  [16] Bagshaw S, Hayman A. Adv. Mater., 2001,13(12/13):1011-1013
17. [17]
  [17] Davis M E. Nature, 2002,417(6891):813-821
18. [18]
  [18] Zhao S X, Lu G Q M, Hu X. Chem. Commun., 1999(15): 1391-1392
19. [19]
  [19] Serrano D P, Aguado J, Garagorri E. Chem. Commun., 2000(20):2041-2042
20. [20]
  [20] Kruk M, Jaroniec M, Sayari A. J. Phys. Chem. B, 1997,101(4):583-589
21. [21]
  [21] Beck J, Vartuli J, Kennedy G, et al. Chem. Mater., 1994,6(10):1816-1821
22. [22]
  [22] Bagshaw S A, Hayman A R. Microporous Mesoporous Mater., 2001,44:81-88
23. [23]
  [23] Ryoo R, Park I S, Jun S, et al. J. Am. Chem. Soc., 2001,123(8):1650-1657
24. [24]
  [24] Wang R, Han S, Hou W, et al. J. Phys. Chem. C, 2007,111(29):10955-10958
25. [25]
  [25] Zhou Y, Antonietti M. Adv. Mater., 2003,15(17):1452-1455
26. [26]
  [26] Zhou Y, Antonietti M. Chem. Mater., 2004,16(3):544-550
27. [27]
  [27] Di Y, Meng X, Wang L, et al. Langmuir, 2006,22(7):3068-3072
28. [28]
  [28] ZENG Tao(曾韬), PENG Shu-Jing(彭淑静). J. Nanjing For. Univ.: Nat. Sci. Ed.(南京林业大学学报:自然科学版), 1996(01):26-28
29. [29]
  [29] CHEN Xiao-Yin(陈晓银), DING Guo-Zhong(丁国忠), CHEN Hai-Ying(陈海鹰), et al. Chem. J. Chinese Universities(高等学校化学学报), 1997(02):186-189
30. [30]
  [30] Brunauer S, Deming L S, Deming W E, et al. J. Am. Chem. Soc., 1940,62(7):1723-1732
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沈阳化工大学材料科学与工程学院沈阳 110142