Citation: XU Jian, XIE Li-Xia, ZHANG Chang-Li. Structures and Magnetic Properties of Two Chiral Polynuclear Metal Clusters with Derivative of L-cysteine[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 807-812. doi: 10.11862/CJIC.2015.102
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An antiferromagnetic complexes based on Co(Ⅱ) or Mn(Ⅱ) and chiral ligand L-thioproline (LTP) with formula of [Co(LTP)2]n (1) and [Mn(LTP)2]n (2) were synthesized and structurally characterized. The ligand LTP forms a five-membered ring upon chelation to the metal ions. In the 2-D structure, each octahedral metal ion is linked to another four metal ions by four LTP ligands adopting a μ2-N1O2:O3 coordination mode. Complexes 1 and 2 are same in the coordination mode and network structure, and crystallize in the orthorhombic crystal system. Magnetic measurements show that a weak antiferromagnetic coupling occurs in the complexes. CCDC: 1042934, 1; 1042935, 2.
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