Citation: LIU Li-Hu, CHEN Shu-Lin, LIU Fan, XIANG Quan-Jun, FENG Xiong-Han, QIU Guo-Hong. Hydrothermal Preparation and Carbon Nanotube Modification of o-LiMnO2 Cathode Materials for Lithium Battery[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 703-709. doi: 10.11862/CJIC.2015.100
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Rechargeable lithium battery cathode materials orthorhombic LiMnO2(o-LiMnO2) was directly synthesized using hydrothermal reaction of MnCl2, LiOH, EDTA and NaClO solutions, and carbon nanotube modified o-LiMnO2(o-LiMnO2/CNTs composite) was further obtained by adding CNTs into the reaction system. The as-prepared samples were characterized by X-ray diffractometer and SEM/TEM, and their electrochemical performance was tested using constant current charge/discharge experiment and cyclic voltammetry. o-LiMnO2 was formed when hydrothermal reaction was performed at 180℃ for 24 h with LiOH/MnCl2 molar ratio as low as 8:1. o-LiMnO2 exhibited the initial discharge capacity of 76.0 mAh·g-1, and cycling capacity of 124.1 mAh·g-1 after 100 cycles. The formation of o-LiMnO2/CNTs composite decreased the particle size and electrochemical resistivity of single o-LiMnO2. The initial discharge capacity was 94.1 mAh·g-1, and increased and then kept stable after 45 cycles, and the cycling capacity was 159.8 mAh·g-1 after 100 cycles. This work facilitates the preparation and electrochemical performance improvement of o-LiMnO2 cathode materials for rechargeable lithium batteries.
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