Citation: LIU Xiu-Xiu, CHENG Mei-Ling, REN Yan-Qiu, XIA Qing-Hong, HAN Wei, LIU Qi. Two Zinc Complexes Based on 1-Carboxymethyl-3,5-dimethyl-1H-pyrazole-4-carboxylic Acid: Syntheses, Structures, and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 611-618. doi: 10.11862/CJIC.2015.098 shu

Two Zinc Complexes Based on 1-Carboxymethyl-3,5-dimethyl-1H-pyrazole-4-carboxylic Acid: Syntheses, Structures, and Luminescent Properties

1.
1 School of Petrochemical Engineering and Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou, Jiangsu 213164, China;
2.
2 State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Received Date: 2 November 2014
Available Online: 31 December 2014
Fund Project: 国家自然科学基金(No.20971060、21101018) (No.20971060、21101018)

One monomeric complex [Zn(4,4'-bpy)(Hcmdpca)₂(H₂O)₃]·2H₂O (1) and one 1D coordination polymer [Zn(4,4'-bpy)(Hcmdpca)₂(H₂O)]·3H₂O (2) (H₂cmdpca=1-carboxymethyl-3,5-dimethyl-1H-pyrazole-4-carboxylic acid, 4,4'-bpy=4,4'-bipyridine) have been synthesized and characterized by elemental analysis, IR spectra, single crystal X-ray diffraction, thermogravimetric analysis. Complexes 1 and 2 all crystallize in the monoclinic system, space group P₂/c. In 1, Zn(Ⅱ) ion is located in distorted octahedral coordination geometry, discrete mononucleate units and water molecules are assembled into a 3D network. In 2, each Zn(Ⅱ) ion is located in distorted square-pyramid geometry. Each 4,4'-bpy ligand bridges two adjacent Zn(Ⅱ) ions, forming a 1D chain. These chains and water molecules are connected by hydrogen bonds, forming a 3D supramolecular network. The thermal stability and luminescent properties of the complexes are also investigated.
- zinc(Ⅱ);1-carboxymethyl-3,5-dimethyl-1H-pyrazole-4-carboxylic acid;4,4'-bipyridine;crystal structure;photoluminescence
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