Citation: LIU Qin-Fu, JI Yang, DU Yan-Na, LI Xiao-Guang, LIANG Peng. Characterization and Deintercalation Kinetics of Kaolinite/γ-Aminopropyltriethoxysilane Intercalation Complex[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 501-508. doi: 10.11862/CJIC.2015.096
-
The kaolinite/γ-aminopropyltriethoxysilane (K/APTES) was prepared with a direct displacement intercalation method by using kaolinite/methanol intercalation complex as an intermediate.The samples were characterized by using X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, and TEM analysis.Analysis suggested that the amidogen of APTES forms hydrogen bonds with tetrahedron siloxane and interlayer methoxy group of the kaolinite/methanol intercalation complex. The APTES molecules are arranged in double layer aslant between the kaolinite layers, and the inclination angle is related to the temperature. Because of hydrogen bonds are broken by APTES, the K/APTES intercalation compound appears clear scroll and exfoliation. The kinetic triplet of APTES' deintercalation from K/APTES intercalation complex was calculated by Satava integral method and Achar-Brindley-Sharp-Wendworth differential method. The activation energy E is 197.8 kJ·mol-1, the logarithm of pre-exponential factor lg(A/s-1) is 14.60. The mechanism function is G(α)=α+(1-α)ln(1-α) and f(α)=[-ln(1-α)]-1.
-
-
[1]
[1] CHEN Shi-Rong(陈世容), QU Wan-Xing(瞿晚星), XU Ka-Qiu(徐卡秋). Silicone Material(有机硅材料), 2003,17(5): 28-31
-
[2]
[2] YANG Shu-Qin(杨淑勤), YUAN Peng(袁鹏), HE Hong-Ping (何宏平), et al. Acta Mineralogica Sinica(矿物学报), 2012, 32(4):10-16
-
[3]
[3] Ledoux R L, White J L. J. Colloid Interface Sci., 1966,21(2): 127-152
-
[4]
[4] Frost R L, Locos O, Kristof J, et al. Vib. Spectrosc., 2001,26 (1):33-42
-
[5]
[5] Frost R L, Kristof J, Kloprogge J T. Spectrochim Acta: Part A, 2001,57:603-609
-
[6]
[6] Mako, Kristof J, Horvath E, et al. J. Colloid Interface Sci., 2009,330(2):367-373
-
[7]
[7] Tsunematsu K, Tateyama H. J. Am. Ceram. Soc., 1999,82(6): 1589-1591
-
[8]
[8] ZHANG Yin-Min(张印民), LIU Qin-Fu(刘钦甫), WU Ze-Guang(伍泽广), et al. J. Chinese Ceram. Soc.(硅酸盐学报), 2011,39(10):113-119
-
[9]
[9] Frost R L, Kristof J, Horvath E, et al. Thermachim Acta, 1999,327(1/2):155-166
-
[10]
[10] Gardolinski J E, Carrera L C M, Cantao M P, et al. J. Mater. Sci., 2000,35(12):3113-3119
-
[11]
[11] Cruz M D R, Franco F. Clays Clay Miner., 2000,48(1):63-67
-
[12]
[12] CHEN Zu-Xiong(陈祖熊), YAN Wei(颜卫), WANG Jian(王 坚), et al. J. Build. Mater.(建筑材料学报), 2000,3(2):151-155
-
[13]
[13] Frost R L, Kristof J, Horvath E, et al. Spectrochim Acta, 2000,56(9):1711-1729
-
[14]
[14] Tonlé I K, Diaco T, Ngameni E, et al. Chem. Mater., 2007, 19(26):6629-6636
-
[15]
[15] Guerra D L, Oliveira S P, Silva R A S, et al. Ceram. Int., 2011,38(2):1687-1696
-
[16]
[16] Komori Y, Enoto H, Takenawa R, et al. Langmuir, 2000,16 (12):5506-5508
-
[17]
[17] FENG Li(冯莉), LIN Zhe(林喆), LIU Jiong-Tian(刘炯天), et al. J. Chinese Ceram. Soc.(硅酸盐学报), 2006,34(10): 1226-1231
-
[18]
[18] DU Xiao-Man(杜小满), LIU Qin-Fu(刘钦甫), CHENG Hong -Fei(程宏飞), et al. China Non-Metallic Min. Ind.(中国非金 属矿工业导刊), 2009(6):12-16
-
[19]
[19] HU Rong-Zu(胡荣祖), SHI Qi-Zhen(史启祯). Thermal Analysis Kinetics(热分析动力学). Beijing: Science Press, 2001.
-
[1]
-
-
[1]
Jing JIN , Zhuming GUO , Zhiyin XIAO , Xiujuan JIANG , Yi HE , Xiaoming LIU . Tuning the stability and cytotoxicity of fac-[Fe(CO)3I3]- anion by its counter ions: From aminiums to inorganic cations. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 991-1004. doi: 10.11862/CJIC.20230458
-
[2]
Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
-
[3]
Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
-
[4]
Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
-
[5]
Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
-
[6]
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
-
[7]
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
-
[8]
Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO2 mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
-
[9]
Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
-
[10]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(227)
- HTML views(41)