基于三羧酸构筑的两个金属-有机骨架(MOFs):合成,晶体结构和性质

引用本文: 赵灿, 张优, 谢梦淋, 吴梦芹, 温一航. 基于三羧酸构筑的两个金属-有机骨架(MOFs):合成,晶体结构和性质[J]. 无机化学学报, 2015, (4): 781-788. doi: 10.11862/CJIC.2015.095 shu

Citation: ZHAO Can, ZHANG You, XIE Meng-Lin, WU Meng-Qin, WEN Yi-Hang. Two Metal-Organic Frameworks Based on Tricarboxylic Acid: Syntheses, Structures and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, 2015, (4): 781-788. doi: 10.11862/CJIC.2015.095 shu

基于三羧酸构筑的两个金属-有机骨架(MOFs):合成,晶体结构和性质

1.
浙江师范大学物理化学研究所, 浙江省固体表面反应化学重点实验室, 金华 321004

通讯作者: 温一航 wyh@zjnu.edu.cn

基金项目:
浙江省自然科学基金(No.LY12B01002) (No.LY12B01002)

浙江师范大学“浙江省省属高校化学重中之重学科”和“先进催化材料教育部重点实验室”开放课题基金项目(No.ZJHX201406) 资助项目。 (No.ZJHX201406)

摘要: 以1,3-二(4'-羧基苯氧基)苯甲酸(H₃L)为配体与金属盐反应,在水热条件下成功合成了2个金属-有机骨架(MOFs),分别为[Cd₂(CH₃COO)(L)(H₂O)₃]_n (1)和[Na(H₂L)]_n (2)。由于H₃L配体配位模式的不同,配合物表现出不同的网络结构。单晶结构分析表明,配合物1属于三斜晶系,P1 空间群,配合物2属于单斜晶系,C2/c空间群。配合物1中Cd²⁺离子的次级构筑单元经由L^3-连接形成三维网络结构。配合物2是一个5-连接的拓扑网络结构,其拓扑符号为(4⁶·6⁴)。此外,还对配合物1的荧光性能进行了分析。

关键词:

金属-有机骨架;1,3-二(4'-羧基苯氧基)苯甲酸;水热合成;拓扑;荧光性能

English

Two Metal-Organic Frameworks Based on Tricarboxylic Acid: Syntheses, Structures and Fluorescent Properties

1.
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: 温一航 wyh@zjnu.edu.cn

Received Date: 13 October 2014
Fund Project:
浙江省自然科学基金(No.LY12B01002)

浙江师范大学“浙江省省属高校化学重中之重学科”和“先进催化材料教育部重点实验室”开放课题基金项目(No.ZJHX201406) 资助项目。

Abstract: Two metal-organic frameworks (MOFs), formulated as [Cd₂(CH₃COO)(L)(H₂O)₃]_n (2) and [Na(H₂L)]_n (2) (H₃L=1,3-bis(4'-carboxylphenoxy)benzoic acid) were successfully prepared by hydrothermal reaction of H₃L ligand with metal salts. Because of the various coordination modes of the H₃L ligand, these compounds display structural diversity. Compound 1 crystallizes in triclinic system with P1 space group and 2 in monoclinic system with C2/c space group. The single crystal structures show that 1 possesses a 3D structural framework, in which the secondary building units(SBUs) are bridged by the L^3- ligands, 2 features a 3D 5-connected network with (4⁶·6⁴) topology. Moreover, the luminescent property of compound 1 has been investigated. CCDC: 1009539, 1; 1009540, 2.

Key words:

metal-organic frameworks;1,3-bis(4'-carboxylphenoxy)benzoic acid;hydrothermal reaction;topology;luminescent property

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于三羧酸构筑的两个金属-有机骨架(MOFs):合成,晶体结构和性质

通讯作者: 温一航 wyh@zjnu.edu.cn

English

Two Metal-Organic Frameworks Based on Tricarboxylic Acid: Syntheses, Structures and Fluorescent Properties

Corresponding author: 温一航 wyh@zjnu.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于三羧酸构筑的两个金属-有机骨架(MOFs):合成,晶体结构和性质

通讯作者: 温一航 wyh@zjnu.edu.cn

English

Two Metal-Organic Frameworks Based on Tricarboxylic Acid: Syntheses, Structures and Fluorescent Properties

Corresponding author: 温一航 wyh@zjnu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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