Citation: LI Ai-Chang, ZHU Ning-Ning, LI Jing-Hong, YANG Xiao-Yan, WANG Shuang, YANG Liu. Preparation of Ag3PO4/Ni Thin Films and Their Photocatalytic Activity and Reaction Mechanism for Rhodamine B[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 681-688. doi: 10.11862/CJIC.2015.094
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Ag3PO4/Ni thin films were prepared by electrochemical method. The surface morphology, phase structure, optical characteristics and band structure of the thin film were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS), respectively. Its photocatalytic properties and stability were evaluated with Rhodamine B (RhB) as a model compound. Using a method of adding active species scavenger to the solution, mechanism of photocatalytic degradation of the film was explored. The results show that the Ag3PO4/Ni thin film prepared under optimum condition has a compact layer structure composed by polymouphous nanoparticles. The thin film exhibits high photocatalytic activity and excellent photocatalytic stability to decompose Rhodamine B. The photodegradation rate is about 2.3 times that of porous P25 TiO2/ITO nanofilm under the visible light in 60 min. The film maintains nearly 100% of their corresponding initial photocatalytic activity after 6 cycles. Furthermore, the photodegradation mechanism of the film for Rhodamine B under the visible light was proposed.
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-
[1]
[1] Antoniadou M, Lianos P. Catal. Today, 2009,144:166-171
-
[2]
[2] Szabo-Bardos E, Zsilak Z, Horvath O. Prog. Colloid Polym. Sci., 2008,135:21-28
-
[3]
[3] María José L M, Rafael V G, José A. Catal. Today, 2005, 101:307-314
-
[4]
[4] XU Yi-Ming(许宜铭). Prog. Chem.(化学进展), 2009,21(2/3): 524
-
[5]
[5] Zou Z, Ye J, Sayama K, et al. Nature, 200l,414(6864):625-627
-
[6]
[6] LU Fei(鲁飞), MENG, Fan-Ming(盂凡明). Bull. Chin. Ceram. Soc. (硅酸盐通报), 2011,30:116-119
-
[7]
[7] YAN Shi-Cheng(闫世成), LUO Wen-Jun(罗文俊), LI Chao-Sheng(李朝升), et al. Mater. China(中国材料进展), 2010, 29(1):1-9
-
[8]
[8] Yi Z G, Ye J H, Kikugawa N, et al. Nat. Mater., 2010,9(7): 559-564
-
[9]
[9] Bi Y P, Hu H Y, Ye J H. et al. Chem. Commun., 2012,48(31):3748-3750
-
[10]
[10] Bi Y P, Hu H Y, Ye J H, et al. Mater. Chem., 2012,22(30): 14847-14850
-
[11]
[11] Bi Y P, Ouyang S, Ye J H, et al. J. Am. Chem. Soc., 2011,133(17):6490-6492
-
[12]
[12] Bi Y P, Ouyang S, Ye J H, et al. Phys. Chem. Chem. Phys., 2011,13(21):10071-10075
-
[13]
[13] Ge M, Zhu N, Zhao Y P, et al. Ind. Eng. Chem. Res., 2012,51(14):5167-5173
-
[14]
[14] Wang H, Bai Y S, Yang J T, et al. Chem. Eur. J., 2012,18(18):5524-5529
-
[15]
[15] Wang W G, Cheng B, Yu J G, et al. Chem. Asian J., 2012,7(8):1902-1908
-
[16]
[16] Liang Q H, Ma W J, Yang X M, et al. CrystEngComm, 2012,14(8):2966-2973
-
[17]
[17] Khan A, Qamar M, Muneer M. Chem. Phys. Lett., 2012,20(25):54-58
-
[18]
[18] Cao J, Luo B D, Lin H L, et al. J. Hazard Mater., 2012,4(1): 107-115
-
[19]
[19] Zhang L L, Zhang H C, Liu Y, et al. New J. Chem., 2012,36(8):1541-1544
-
[20]
[20] Dinh C T, Nguyen T D, Kleitz F, et al. Chem. Commun., 2011,47(32):7797-7799
-
[21]
[21] Umezawa N, Ouyang S, Ye J. Phys. Rev.: B, 2011,83(3): 035202-1-035202-6.
-
[22]
[22] Esquivel K, Arriaga LG, Rodriguez F J, et al. Water Res., 2009,43:3593-3603
-
[23]
[23] YANG Yong-Biao(杨勇彪), ZHANG Zheng-Fu(张正富), CHEN Qing-Hua(陈庆华), et al. Yunnan Metallurge(云南冶金), 2004,33(4): 20-22
-
[24]
[24] LI Ai-Chang(李爱昌), LU Yan-Hong(卢艳红), CHEN Rong-Ying(陈荣英), et al. J. Chin. Ceram. Soc.(硅酸盐学报), 2014,42(6):808-815
-
[25]
[25] GUO He-Tong(郭鹤桐), LIU Shu-Lan(刘淑兰). Theoretical Electrochemistry(理论电化学). Beijing: China Astronautic Publishing Press, 1984:240,67
-
[26]
[26] FAN Xong(范雄). Metal X-ray Diffractometry(金属X射线衍射学). Beijing: China Machine Press, 1996:45
-
[27]
[27] WANG Yun-Fang(王韵芳), FAN Cai-Mei(樊彩梅). Chinese J. Inorg. Chem.(无机化学学报), 2012,28(2):347-351
-
[28]
[28] Liu J J, Fu X L, Chen S F, et al. Appl. Phys. Lett., 2011,99: 191903(1-3)
-
[29]
[29] LIU Jian-Xin(刘建新), WANG Yun-Fang(王韵芳), WANG Ya-Wen(王雅文), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2014,30(4):729-737
-
[30]
[30] WU Hao-Qing(吴浩青), LI Yong-Fang(李永舫). Electrochemical Kinetics(电化学动力学). Beijing: Higher Education Press, 1998:178
-
[31]
[31] XU Xiu-Quan(徐秀泉), YU Xiao-Feng(于小凤), TANG Yan (唐燕), et al. J. Chin. Ceram. Soc.(硅酸盐学报), 2012,40(12):1796-1801
-
[32]
[32] Wang B, Gu X Q. Key Eng. Mater., 2014,609:335-340
-
[33]
[33] LI Ai-Chang(李爱昌),LI Gui-Hua(李桂花), ZHENG Yan (郑琰), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2012, 28(2):457-464
-
[34]
[34] LI Ai-Chang(李爱昌), LI Jian-Fei(李健飞), LIU Ya-Lu (刘亚录), et al. Acta Chim. Sinica (化学学报), 2013,71(5): 815-821
-
[35]
[35] YANG Juan(杨娟), DAI Jun(戴俊), ZHAO Jin-Cai(赵进才), et al. Chin. Sci. Bull.(科学通报), 2009,54(15):2196-2204
-
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