Citation: GU Xiao-Min, WANG Lei, SHAN Yue-Xia, ZHANG Wen-Li, CHEN Qin, NI Liang, YAO Jia. Frameworks of Metal Dicarboxylate Complexes: from Nuclear Structures to Double Chains Based on N-containing Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 555-564. doi: 10.11862/CJIC.2015.091
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Three complexes have been obtained by the reaction of metal (Mn(Ⅱ), Cd(Ⅱ)), 5,6-substituted 1,10-phen derivatives with two carboxylic acids, 4,4'-oxybis(benzoic acid)(4,4'-H2oba) and oxalic acid (H2ox). The crystal structures of the resulting complexes, namely {[Mn(4,4'-oba)(Medpq)]Medpq}n (1), [Mn2(4,4'-oba)2(MOPIP)4]·2H2O (2), and [Cd(ox)(MOPIP)2]·2H2O (3) (Medpq=2-methyldipyrido-[3,2-f:2,3'-h]quinoxaline, MOPIP=2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline]), have been elucidated using their single-crystal X-ray diffraction analysis. Diverse structures are observed for these complexes. Compound 1 contains double chains, which are further stacked via hydrogen bonding interactions to form layers. Compound 2 features dinuclear structures, which are connected by strong π…π and hydrogen bonding interactions to result in layer structures. Compound 3 contains mononuclear structures and extended to chain and layer structures by π…π and hydrogen bonding interactions. The differences among these structures indicate that the size of the rigid chelating ligands and the flexibility of carboxylate have important effects on the structures of their complexes. The fluorescent properties of 2 and 3 were studied in the solid state at room temperature.
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