Citation: JING Xu, YANG Lin-Lin, CHANG Zhi-Duo, HE Cheng, DUAN Chun-Ying. Photocatalytic Hydrogen Production from Water Using Cobalt-Thiosemicarbazone Complex as Redox Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 975-980. doi: 10.11862/CJIC.2015.090
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By incorporating a phosphine donor within a thiosemicarbazone moiety to enhance the coordinated ability of the chelators, a cobalt complex Co-NSP (HNSP: 4-[2-(2-diphenylphosphino-benzylidene) thiosemicar-bohydrazone]benzenesulfonate) was obtained as the proton reduction catalyst for light driven H2 evolution in homogeneous environment with fluorescein as the photosensitizer. The presence of NSP tridentate chelator benefits the formation of low oxidized species to increase the catalytic efficiency, and the incorporation of a sulfonate group enhances the water solubility of the catalyst. The amount of H2 generation in 12 h photolysis maximizes in the presence of sacrificial reagent NEt3 at pHvalue of 11.0. The initial TOF (turnover frequency) is about 200 mol H2 per mole catalyst per hour with the turnover number (TON) about 2000 mol H2 per mole of catalyst.
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