Citation: YANG Dai-Sheng, XU Li-Hua, CHEN Hui, ZHANG Li-Fang, NI Zhong-Hai, WANG Wen-Feng. Synthesis, Crystal Structure and Magnetic Properties of a One-Dimensional Cyanide-Bridged CrⅢ-CuⅡ Complex {[Cu(cyclam)][Cr(bpb)(CN)2]2·2H2O}n[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 565-570. doi: 10.11862/CJIC.2015.089
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A one-dimensional cyanide-bridged CrⅢ-CuⅡ complex {[Cu(cyclam)][Cr(bpb)(CN)2]2·2H2O}n (cyclam=1, 4,8, 11-tetraazacyclotetradecane, bpb2-=1,2-bis(pyridine-2-carboxamido)-benzenate) (1) has been synthesized by the reaction of building blocks [Cu(cyclam)](ClO4)2 and K[Cr(bpb)(CN)2]. Single crystal X-ray diffraction analysis reveals that complex 1 crystallizes in triclinic space group P1 with a=0.966 73(19) nm, b=1.345 1(3) nm, c= 1.382 0(3) nm, α=77.12(3)°, β=76.93(3)°, γ=82.02(3)°, V=1.699 1(6) nm3, Z=2, Dc=1.567 g·cm-3, μ=1.086 mm-1, F(000)=828, R1=0.041 3, wR2=0.120 0, the structure of complex 1 is a type of polymer with two different metal centers which are alternatively linked by cyanide group. Magnetic investigations indicate that complex 1 exhibits a weak ferromagnetic coupling between CrⅢ and CuⅡ centers through the cyanide bridge.
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