Citation: GUAN Ming-Yun, JIAN Yan, SUN Jian-Hua, XU Zheng. Flower-Like Mesocrystal Cobalt: Controllable Synthesis in Large Scale and Magnetic Property[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 619-626. doi: 10.11862/CJIC.2015.084 shu

Flower-Like Mesocrystal Cobalt: Controllable Synthesis in Large Scale and Magnetic Property

GUAN Ming-Yun ^1,2 ,
JIAN Yan ¹ ,
SUN Jian-Hua ^1,2 ,
XU Zheng ²

1.
1 Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, Jiangsu 213001, China;
2.
2 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Received Date: 3 November 2014
Available Online: 23 December 2014
Fund Project: 国家973重点建设项目基础研究项目(No.2007CB936302) (No.2007CB936302) 国家自然科学基金-面上项目(No.21373103) (No.21373103) 江苏省自然科学基金-面上项目 (No.BK2011260)资助项目。 (No.BK2011260)

Using diethylenetriamine (DETA) as coordination agent, a well-defined flower-like cobalt mesocrystal was synthesized rapidly by nanoparticles self assembly in oriented fashion. By adjusting reaction rate and kind of coordination agents, morphologies of cobalt can be transformed from nice-look flower, via poor-look dendrite, to microsphere composed of nanoparticles or nanoplates. DETA plays an important role in the formation process of cobalt mesocrystal. The possible formation mechanism is proposed. The cobalt mesocrystals not only exhibit Co nanocrystals property (an enhanced coercive force being 260 Oe at 300 K), but also have bulk Co property (saturation magnetization being 168 emu·g^-1). The synthesis method in large scale is facile and effective with high yield.
- cobalt;crystallization assembly;mesocrystal;oriented attachment
1. [1]
  [1] Ma M G, Cölfen H. Curr. Opin. Colliod Interface Sci., 2014, 19:56-65
2. [2]
  [2] Cölfen H, Antonietti M. Angew. Chem. Int. Ed., 2005,44: 5576-5591
3. [3]
  [3] Meldrum F C, Cölfen H. Chem. Rev., 2008,108:4332-4432
4. [4]
  [4] Zhou L, O'Brien P. Small, 2008,4:1566-1574
5. [5]
  [5] Zhou L, Smyth-Boyle D, O'Brien P. J. Am. Chem. Soc., 2008, 130:1309-1320
6. [6]
  [6] Li T, You H J, Xu M W, et al. Appl. Mater. Interfaces, 2012, 4:6942-6948
7. [7]
  [7] (a)Oaki Y, Imai H. Small, 2006,2:66-70
8. [8]
  (b)Popovic J, Cakan R D, Tornow J, et al. Small, 2011,7:1127-1135
9. [9]
  [8] Yao R M, Cao C B, Bai J. CrystEngComm, 2013,15:3279-3283
10. [10]
  [9] Ye J F, Liu W, Cai J G, et al. J. Am. Chem. Soc., 2011,133: 933-940
11. [11]
  [10] Mo M S, Lim S H, Mai Y W, et al. Adv. Mater., 2008,20: 339-342
12. [12]
  [11] (a)Li Z H, Gener André, Richters J P, et al. Adv. Mater., 2008,20:1279-1285
13. [13]
  (b)Wang S S, Xu A W. CrystEngComm, 2013,15:376-381
14. [14]
  (c)Liu Z, Wen X D, Wu X L, et al. J. Am. Chem. Soc., 2009, 131:9405-9412
15. [15]
  [12] Zhou N, Uchaker E, Wang H Y, et al. RSC Adv., 2013,3: 19366-19374
16. [16]
  [13] Sun J X, Chen G, Pei J, et al. J. Mater. Chem., 2012,22: 5609-5614
17. [17]
  [14] (a)Tachikawa T, Zhang P, Bian Z F, et al. J. Mater. Chem. A, 2014,2:3381-3388
18. [18]
  (b)Thachepan S, Li M, Mann S. Nanoscale, 2010,2:2400-2405
19. [19]
  [15] Jongen N, Bowen P, Lemaitre J, et al. J. Colloid Interface Sci., 2000,226:189-198
20. [20]
  [16] Johannes I, Bots P, Kulak A, et al. Adv. Funct. Mater., 2013,23:1965-1973
21. [21]
  [17] Yuwono V M, Burrows N D, Soltis J A, et al. J. Am. Chem. Soc., 2010,132:2163-2165
22. [22]
  [18] Zhou Y, Wang X Y, Wang H, et al. Dalton Trans., 2014,43: 4711-4719
23. [23]
  [19] Dang F, Hoshino T, Oaki Y Y, et al. Nanoscale, 2013,5: 2352-2357
24. [24]
  [20] Song R Q, Xu A W, Antonietti M, et al. Angew. Chem. Int. Ed., 2009,48:395-399
25. [25]
  [21] Liu Y Q, Kumar A, Fan Z, et al. Appl. Phys. Lett., 2013, 102:232903(1-5)
26. [26]
  [22] (a)Fang J X, Ding B J, Song X P. Appl. Phys. Let., 2007,91: 083108(1-3)
27. [27]
  (b)Fang J X, Ding B J, Song X P, et al. Appl. Phys. Lett., 2008,92:173120(1-3)
28. [28]
  (c)Fang J X, Ding B J, Song X P. Cryst. Grow. Des., 2008,8: 3617-3622
29. [29]
  [23] Fang Z, Long L Y, Hao S H, et al. CrystEngComm, 2014, 16:2061-2069
30. [30]
  [24] (a)Guo X H, Yu S H. Cryst. Grow. Des., 2007,7:354-359
31. [31]
  (b)Guan M Y, Zhu G X, Shang T M, et al. CrystEngComm, 2012,14,6540-6547
32. [32]
  [25] (a)Wang M S, Zhang Y P, Zhou Y J, et al. CrystEngComm, 2013,15:754-763
33. [33]
  (b)Park N H, Wang Y F, Seo W S, et al. CrystEngComm, 2013,15:679-685
34. [34]
  [26] Puntes V F, Krishnan K M, Alivisatos A P. Science, 2001, 291:2115-2117
35. [35]
  [27] Xiemuxiding Abula(谢木西丁·阿布拉), Beysen Sadeh(拜山·沙德克), Mutila Aman(木提拉·阿曼), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(7):1403-1408
36. [36]
  [28] HE Wen-Qi(贺文启), XIAO Yong(肖勇), CHENG Jia-Liang (成嘉亮), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(9):1685-1689
37. [37]
  [29] An K, Lee N, Park J, et al. J. Am. Chem. Soc., 2006,128: 9753-9760
38. [38]
  [30] YANG Pei-Xia(杨培霞), AN Mao-Zhong(安茂忠), SU Cai-Na(苏彩娜), et al. Chinese J. Inorg. Chem.(无机化学学报), 2007,23(9):1501-1504
39. [39]
  [31] Liu X, Yi R, Wang Y, et al. J. Phys. Chem. C, 2007,111: 163-167
40. [40]
  [32] Zhu L P, Xiao H M, Zhang W D, et al. Cryst. Growth Des., 2008,8:1113-1118
41. [41]
  [33] Cao M H, Liu T F, Gao S, et al. Angew. Chem. Int. Ed., 2005,44:4197-4201
42. [42]
  [34] Bao J C, Tie C Y, Xu Z, et al. Adv. Mater., 2002,14:44-47
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