Citation: Lotfia-El Majdoub, YAO Fang-Tao, SHI Ya-Sai, LI Tian-Tian, XU Qing-Hong. Supporting of Fe³⁺ on Surface of Activated Silica Gel and Its Catalytic Oxidation Performance to Formaldehyde[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 479-484. doi: 10.11862/CJIC.2015.082 shu

Supporting of Fe³⁺ on Surface of Activated Silica Gel and Its Catalytic Oxidation Performance to Formaldehyde

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of ChemicalTechnology, Beijing 100029, China

Corresponding author: XU Qing-Hong,
Received Date: 20 August 2014
Available Online: 2 November 2014
Fund Project: 国家自然科学基金(No.U1362113)资助项目。 (No.U1362113)

After heated at 400 ℃, the activated silica gel reacted with silicon tetrachloride to obtain chlorinated silica gel in anhydrous tetrahydrofuran. And a modified silica gel with carbonyl and amino groups on its surface was obtained by the reaction between chlorinated silica gel and acetamide. The modification has good coordination ability to Fe³⁺, and a supported catalyst with catalytic active site of Fe³⁺ evenly distributed was then prepared by coordination between Fe³⁺ and the surface organic modified silica gel. The synthesized catalyst has good catalytic oxidation performance to formaldehyde, and a maximum conversion of formaldehyde is about 91.3%.
- activated silica gel;organic surface;supported;catalytic oxidation;formaldehyde
1. [1]
  [1] Johnson L K, Killian C M, Brookhart M. J. Am. Chem. Soc., 1995,117:6414-6415
2. [2]
  [2] Dong L J, Ge C L, Qin P Y, et al. Solid State Sci., 2014,31: 8-15
3. [3]
  [3] Saleh J M, Hussian S M. J. Chem. Soc., Faraday Trans., 1986,82(1):2221-2234
4. [4]
  [4] Christoskova S G, Danova N, Georgieva M, et al. Appl. Catal. A: Gen., 1995,128(2):219-229
5. [5]
  [5] Sekine Y, Nishimura A. Atmos. Environ., 2001,35(11):2001-2007
6. [6]
  [6] Álvarez-Galván M C, de la Peña O'Shea V A, Fierro J L G, et al. Catal. Commun., 2003,4(5):223-228
7. [7]
  [7] TANG Xin-Fu(唐幸福), HUANG Xiu-Min(黄秀敏), SHAO Jian-Jun(邵建军), et al. Chinese J. Catal.(催化学报), 2006, 2:97-99
8. [8]
  [8] Chen H, He J, Zhang C, et al. J. Phys. Chem. C, 2007,111 (49):18033-18038
9. [9]
  [9] Chen T, Dou H Y, Li X L, et al. Microporous Mesoporous Mater., 2009,122(1/2/3):270-274
10. [10]
  [10] Yang J J, Li D X, Zhang Z, et al. J. Photochem. Photobiol., A: Chem., 2000,137:197-202
11. [11]
  [11] Tang X, Li Y, Huang X, et al. Appl. Catal. B: Environ, 2006,62(3/4):265-273
12. [12]
  [12] Kecsk S T, Rask J, Kiss J. Appl. Catal. A: Gen., 2004,273 (1/2):55-62
13. [13]
  [13] ZHang J, Jin Y, Li C, et al. Appl. Catal. B: Environ., 2009, 91(1/2):11-20
14. [14]
  [14] Gurubasavaraj P M, Roesky H W. Inorg. Chem., 2008,47 (12):5324-5331
15. [15]
  [15] Zhuravlev L T. Colloids Surf. A, 1993,74:7190
16. [16]
  [16] WU Li-Qiang(武利强), YAN Fu-Lin(闫福林), YANG Chun-Guang (杨春广), et al. Chinese J. Org. Chem.(有机化学), 2010,30(11):1764-1767
17. [17]
  [17] JIA Yun-Jie(贾云洁), LI Ming-Lei(李明磊), CUI Ji-Li(崔纪利), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29 (3):465-473
1. [1]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
2. [2]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
3. [3]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
6. [6]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
7. [7]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
8. [8]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
9. [9]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
10. [10]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
11. [11]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
12. [12]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
13. [13]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
14. [14]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
15. [15]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
16. [16]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
17. [17]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
18. [18]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
19. [19]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
20. [20]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(161)
HTML views(20)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Supporting of Fe3+ on Surface of Activated Silica Gel and Its Catalytic Oxidation Performance to Formaldehyde

Metrics

通讯作者: 陈斌, bchen63@163.com

Supporting of Fe³⁺ on Surface of Activated Silica Gel and Its Catalytic Oxidation Performance to Formaldehyde