Citation: ZHANG Zhuo-Ming, YANG Jiang-Feng, WANG Yong, LI Jin-Ping. Effect of Water Molecules on Structure and Properties of Metal-Organic Frameworks[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 627-634. doi: 10.11862/CJIC.2015.075 shu

Effect of Water Molecules on Structure and Properties of Metal-Organic Frameworks

1.
Research Institute of Fine Chemicals, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: LI Jin-Ping,
Received Date: 14 October 2014
Available Online: 25 December 2014
Fund Project: 国家自然科学基金项目(No.21136007、51302184) (No.21136007、51302184)973前期专项(2014CB260402)项目资助。 (2014CB260402)

Metal-organic frameworks (MOFs) is a new class of organic-inorganic hybrids. MOFs have exhibited the attractive prospects in many fields, such as the gas adsorption and separation, the catalysts, the magnetism and the bio-medicine. However, its performance will be greatly affected in the humid environment, which hindered its industrialization process. Firstly, this paper describes the destruction mechanism of MOFs at the presence of water molecules, and we summarize the elements of MOFs structure stability at the presence of water based on their two structural elements; And then, this paper summarizes the adsorption mechanism of water molecules on MOFs and the influence of it; Finally, we made a prospect of the MOF-water issue in order to provide a reference for future research.
- metal-organic frameworks(MOFs);hydrolysis;adsorbed;water molecules
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