Citation: LIU Hai-Rui, FANG Li-Yu, JIA Wei, JIA Hu-Sheng. Fabrication of ZnS Nanoparticles with Enhanced Photocatalytic Activity by Hydrothermal Method[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 459-464. doi: 10.11862/CJIC.2015.074
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Under the role of CTAB, different size ZnS spherical-like particles were fabricated by hydrothermal method. The crystal structure, morphology, composition and optical property of the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), X-ray energy spectrum (EDS), UV-Vis absorption spectrum and photoluminescence spectrum (PL). Photocatalytic activities were evaluated by degradation of MB solution. The results show that ZnS nanoparticles were formed by aggregation of crystal nucleus under the role of CTAB. With the increase of reaction time, the size of ZnS particles increased to 500 nm, however, the crystal structure of product has no change. With the increase of particle size, the UV-Vis absorption peak of samples shifted from 418 to 362 nm and the PL intensity further increased. Finally, the photocatalytic activity presented that fabricated ZnS nanoparticles with reaction time 12 h showed best photcatalytic performance.
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