Citation: QU Xing-Yu, CHEN Wei, SHI Mao-Hu, SHEN Zhen. Synthesis and Properties of Red fluorescent Probe for Fe³⁺ Based on Boron-Dipyrromethene Dimer[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 580-584. doi: 10.11862/CJIC.2015.072 shu

Synthesis and Properties of Red fluorescent Probe for Fe³⁺ Based on Boron-Dipyrromethene Dimer

QU Xing-Yu ^1,2 ,
CHEN Wei ¹ ,
SHI Mao-Hu ¹ ,
SHEN Zhen ¹

1.
1 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
2.
2 College of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030600, China

Received Date: 6 October 2014
Available Online: 12 December 2014
Fund Project: 国家自然科学基金(No．21371090)资助项目。 (No．21371090)

A red fluorescence boron-dipyrromethene (BODIPY, BODIPY core=4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) dimer 1, which is linked through β-β (2/6) position from a coupling reaction, exhibits efficient energy transfer with 222 nm pseudo Stokes' shift. The BODIPY dimer 1 shows high selectivity and sensitivity towards Fe (Ⅲ) when the ion co-exsists with common interfering metal ions and it may be used as an indicator for Fe³⁺.
- Boron-dipyrromethene (BODIPY) dyes;fluorescent sensor;red visible;energy transfer;Fe³⁺
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Synthesis and Properties of Red fluorescent Probe for Fe3+ Based on Boron-Dipyrromethene Dimer

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Properties of Red fluorescent Probe for Fe³⁺ Based on Boron-Dipyrromethene Dimer