Citation: TANG Li-Zhi-Peng, YANG Ming-Wei, CHENG Mei-Ling, LIU Qi. Syntheses, Crystal Structures and Luminescent Properties of Two Cadmium Supramolecular Complexes Based on Water-Carboxylate Chains[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 603-610. doi: 10.11862/CJIC.2015.070 shu

Syntheses, Crystal Structures and Luminescent Properties of Two Cadmium Supramolecular Complexes Based on Water-Carboxylate Chains

1.
1 School of Petrochemical Engineering and Jiangsu Key Labroratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou, Jiangsu 213164, China;
2.
2 State Key Labroratory of Coordination, Nanjing University, Nanjing 210093, China

Corresponding author: CHENG Mei-Ling,
Received Date: 14 October 2014
Available Online: 12 December 2014
Fund Project: 江苏省高校自然科学研究面上项目(No.13KJB150001) (No.13KJB150001)

Two cadmium supramolecular complexes, [Cd(HMPCA)₂(2,2'-bpy)]·2H₂O (1) and [Cd(HMPCA)₂(phen)]·2.5H₂O (2) (H₂MPCA=5-methyl-1H-pyrazole-3-carboxylic acid, 2,2'-bpy=2,2'-bipyridine, phen=1,10-phenanthro-line), have been synthesized and characterized by elemental analysis, IR spectra and X-ray diffraction analysis. In 1 and 2, the mononuclear units are expanded to 3D supramolecular structures via O(C, N)-H…O hydrogen bonds, C-H…π interaction and π…π interaction. More interestingly, the water-carboxylate hydrogen bonded chains constructed by lattice water molecules and carboxylate groups play important role in the assembly of two supramolecular complexes. Besides, the thermal and luminescent properties of two complexes were also investigated.
- cadmium;water cluster;luminescent property;5-methyl-1H-pyrazole-3-carboxylic acid;crystal structure
1. [1]
  [1] Zhang J P, Zhang Y B, Lin J B, et al. Chem. Rev., 2012, 112:1001-1033
2. [2]
  [2] Zhang X T, Sun D, Li B, et al. Cryst. Growth Des., 2012,12: 3845-3848
3. [3]
  [3] Evans O, Lin W B. Acc. Chem. Res., 2002,35:511-522
4. [4]
  [4] Liu Q, Yu L L, Wang Y, et al. Inorg. Chem., 2013,52(6):2817 -2822
5. [5]
  [5] Luo G, Xiong H, Sun D, et al. Cryst. Growth Des., 2011,11: 1948-1956
6. [6]
  [6] Hao H, Sun D, Liu F, et al. Cryst. Growth Des., 2011,11: 5475-5482
7. [7]
  [7] Sun D, Xu H, Yang C, et al. Cryst. Growth Des., 2010,10: 4642-4649
8. [8]
  [8] Du M, Jiang X J, Zhao X J. Chem. Commun., 2005:5521-5523
9. [9]
  [9] Zhang X T, Fan L M, Sun Z, et al. Cryst. Growth Des., 2013, 13:792-803
10. [10]
  [10] Zhang Q L, Feng G W, Zhang Y Q, et al. RSC Adv., 2014, 4:11384-11392
11. [11]
  [11] Fan L M, Zhang X T, Zhang W, et al. CrystEngComm, 2014, 16:2144-2157
12. [12]
  [12] WANG Zhi-Yong(王志勇), WANG Wei-Ming(王卫民), LI Gang(李刚). Chinese J. Inorg. Chem.(无机化学学报), 2014, 30:366-370
13. [13]
  [13] Shi X, Zhu G S, Wang X H, et al. Cryst. Growth Des., 2005, 5:341-346
14. [14]
  [14] Zhang X T, Fan L M, Zhao X, et al. CrystEngComm, 2012, 14:2053-2061
15. [15]
  [15] BAO Jin-Ting(包金婷), CHENG Mei-Ling(程美令), LIU Qi (刘琦), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013, 29:1504-1512
16. [16]
  [16] Sheldrick G M. SHELXS-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.
17. [17]
  [17] LI Guo-Feng(李国峰), LI Xiu-Mei(李秀梅), JI Jian-Ye(纪建业), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014, 30:1947-1953
18. [18]
  [18] HAN Wei(韩伟), CHENG Mei-Ling(程美令), LIU Qi(刘琦), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28: 1997-2004
19. [19]
  [19] Fan L M, Zhang X T, Li D, et al. CrystEngComm, 2013,15: 349-355
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沈阳化工大学材料科学与工程学院沈阳 110142