Citation: GU Shao-Nan, LI Wen-Jun, LUO Wen-Li, CHANG Zhi-Dong, ZHOU Hua-Lei. Hydrophobic ZnO: Low Temperature Complex-Precipitate Synthesis and Application in Improving Foam Stability[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 594-602. doi: 10.11862/CJIC.2015.069 shu

Hydrophobic ZnO: Low Temperature Complex-Precipitate Synthesis and Application in Improving Foam Stability

1.
1 Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, University of Science and Technology Beijing, Beijing 100083, China;
2.
2 Research Institute of Petroleum Exploration and Development, Petro China, Beijing 100083, China

Corresponding author: LI Wen-Jun,
Received Date: 17 October 2014
Available Online: 16 December 2014
Fund Project: 国家自然科学基金(No. 21276022)资助项目。 (No. 21276022)

Using Zn(NO₃)₂·6H₂O as raw material, 25% ammonia as complexing agent and NaOH as precipitant, ZnO micro-spheres were synthesized by low temperature complex-precipitate(LTCP) method. The species distribution in the system was also analyzed. XRD and SEM were employed to characterize ZnO samples. The SEM images demonstrate that the uniform micro-spheres are about 2 μm. The morphology of the samples appears as micro-rods and as irregular polyhedrons without addition of NaOH or ammonia. ZnO micro-spheres were hydrophobically modified by varies amounts of cetyltrimethylammonium bromide(CTAB) in order to obtain different contact angles. Meanwhile, the process for surfactant molecules absorption on ZnO micro-spheres surface was discussed. The results of foam stability reveal that 0.03wt% ZnO micro-sphere with surface contact angle of 52.9° makes the greatest contribution to improving the stability of foams.
- zinc oxide;complex-precipitate;morphology tunable;hydrophobic effect;foam stability
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