Citation: FAN Hui-Tao, LI Bo, ZHAO Qiang, CHEN Bao-Kuan, FENG Chao-Qiang. Zinc and Cadmium Coordination Polymers Based on 3-(Carboxymethoxy)benzene-1, 2-dioic Acid and N-donor Ancillary Ligands: Syntheses, Crystal Structures, and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 848-856. doi: 10.11862/CJIC.2015.068 shu

Zinc and Cadmium Coordination Polymers Based on 3-(Carboxymethoxy)benzene-1, 2-dioic Acid and N-donor Ancillary Ligands: Syntheses, Crystal Structures, and Luminescent Properties

1.
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China

Received Date: 21 November 2014
Available Online: 16 December 2014
Fund Project: 河南省教育厅科学技术研究重点项目基础研究计划(No.14A150026) (No.14A150026)南阳师范学院高层次人才科研启动费(No.ZX2014041)项目资助。 (No.ZX2014041)

Two coordination polymers, {[Zn₇(L)₄(bpe)₂(μ₃-OH)₂(H₂O)₈]·4H₂O}n (1), and {[Cd₃(L)₂(bpy)_2.5(H₂O)]·5.5H₂O}_n (2) (H₃L=3-(carboxymethoxy)benzene-1,2-dioic acid, bpe=1,2-bis(4-pyridyl)-ethene, and bpy=4,4'-bipyridine), have been synthesized under hydrothermal condition. Both complexes were characterized by elemental analysis, IR spectra, thermogravimetric analysis (TGA), and single-crystal X-ray crystallography. Complex 1 features a three-dimensional supramolecular architecture linked through hydrogen bonding interactions in which the secondary building unit (SBU) is [Zn₅(μ₃-OH)₂] cluster. Complex 2 features three-dimensional metal-organic framework with (3,3,6)-connected topology. The luminescence behaviors of 1 and 2 were also discussed. CCDC: 965303, 1; 965304, 2.
- 3-(carboxymethoxy)benzene-1,2-dioic acid;crystal structure;luminescence properties;topology
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沈阳化工大学材料科学与工程学院沈阳 110142