Citation: SHENG Jun-Feng, WANG Ning, CAI LIANG-Ying, SONG Fei, TONG Yu-Zhu, QU Zhi-Rong, WANG Zuo-Xiang. Syntheses, Crystal Structures, and Spectral Properties of Copper(Ⅱ) and Cadmium(Ⅱ) Complexes with3-Phenoxymethyl-4-(4-methyphenyl)-5-(2-pyridyl)-1,2,4-triazole[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 405-412. doi: 10.11862/CJIC.2015.062 shu

Syntheses, Crystal Structures, and Spectral Properties of Copper(Ⅱ) and Cadmium(Ⅱ) Complexes with3-Phenoxymethyl-4-(4-methyphenyl)-5-(2-pyridyl)-1,2,4-triazole

1.
1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China;
2.
2. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China

Corresponding author: WANG Zuo-Xiang,
Received Date: 29 September 2014
Available Online: 7 December 2014
Fund Project: 企业合作基金(No.8507040052)资助项目 (No.8507040052)

Two complexes [Cu₂L₂Cl₄]·2H₂O (1) and [Cd₃L₂( μ₂-Cl)₆]_n·2nCH₃CN (2) were obtained by the reaction of 3-phenoxymethyl-4-(4-methyphenyl)-5-(2-pyridyl)-1,2,4-triazole (L) with Copper(Ⅱ) chloride and cadmium(Ⅱ) chloride respectively. The complexes have been characterized by IR, UV, TGA, powder XRD, elemental analyses and crystal structures. The complexes 1 and 2 crystallize in the triclinic space group P1. Crystallographic studies reveal that 1 has a distorted trigonal bipyramidal [CuN₃Cl₂] coordination. 2 is a polymeric complex. every repeat unit has three cadmium(Ⅱ) atoms and two different cadmium(Ⅱ) centers. Cd1(Ⅱ) atom possesses a centrosymmetric distorted-octahedral geometry with [CdCl₂Cl'₂N₂], and Cd2(Ⅱ) atom has a distorted-octahedral geometries with [CdCl₂Cl'Cl″NN']. CCDC: 1015366, L; 1015367, 1; 1015368, 2.
- copper(Ⅱ) complex;cadmium(Ⅱ) complex;crystal structures;triazole
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沈阳化工大学材料科学与工程学院沈阳 110142