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Citation: LI Xin, ZHOU Shang-Yong, TIAN Li. Zinc(Ⅱ) Coordination Polymers Based on Aromatic Tetracarboxylate: Syntheses, Structures, and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 338-344. doi: 10.11862/CJIC.2015.057 shu

Zinc(Ⅱ) Coordination Polymers Based on Aromatic Tetracarboxylate: Syntheses, Structures, and Properties

  • 1.

    Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China

  • Corresponding author: TIAN Li, 
  • Received Date: 11 August 2014
    Available Online: 25 November 2014

    Fund Project: 国家自然科学基金(No.21371133) (No.21371133)天津市自然科学基金资助项目(No.12JCZDJC27600)资助项目 (No.12JCZDJC27600)

  • Two coordination compounds, namely {[Zn2(bptc)(DMF)2(H2O)]·DMF·H2O}n(1) and{[Zn(bte)(bptc)0.5]·DMF·0.5H2O}n(2) (bte=bis(1,2,4-triazol-1-yl)ethane, H4bptc=biphenyl-3,3',5,5'-tetracarboxylic acid), have been synthesized and structurally characterized. 1 features a 3Dframework with PtS-type topology, in which each binuclear second-building-unit (SBU){Zn2(O2CR)4} is linked to four biphenyl connectors (and vice versa). 2 is 2Dlayers, which are interconnected by weak C-H…Ointeractions to lead to 3Dsupramolecular framework. The thermal stability, and fluorescent emission of the two complexes have also been discussed. CCDC:1018691, 1; 1018790, 2.
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