Citation: JIN Chao, WANG Yin-Ge, QIAN Hui-Fen, HUANG Wei. A Cu(Ⅱ) Complex with₂,9-Dithienyl^-1,10-phenanthroline-5,6-dione Ligand with Large Steric Hindrance[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 413-419. doi: 10.11862/CJIC.2015.054 shu

A Cu(Ⅱ) Complex with₂,9-Dithienyl^-1,10-phenanthroline-5,6-dione Ligand with Large Steric Hindrance

JIN Chao ¹ ,
WANG Yin-Ge ¹ ,
QIAN Hui-Fen ^1,2,, ,
HUANG Wei ^2,,

1.
1. College of Sciences, Nanjing Tech University, Nanjing 210009, China;
2.
2. State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: QIAN Hui-Fen, HUANG Wei,
Received Date: 7 September 2014
Available Online: 7 October 2014
Fund Project: 国家自然科学基金(No.21171088) (No.21171088)

1,10-Phenanthroline-5,6-dione based molecules (1 and 2), extended by two thiophene rings at 2 and 9 positions, have been designed and prepared successfully. It is interesting to mention that the study of coordination chemistry of this large steric ligand 2 with some transition-metal ions reveals that only a Cu(Ⅱ) complex 3·H₂Ocan be yielded. The conformation of ligand 2 undergoes great alteration after Cu(Ⅱ) ion complexation, where the dihedral angles between the central 1,10-phenanthroline-5,6-dione and its neighboring two thiophene rings are significantly increased from 1.9(2)°/5.6(2)° in 2 and 5.2(6)°/6.5(6)° in 2·CHCl3 to 25.3(3)°/27.2(3)° and 34.9(3)°/38.2(3)° in 3·H₂O in order to meet the geometric requirement of four-coordinate Cu(Ⅱ) centre. CCDC: 1013452, 2; 1013453, 2·CHCl3; 1013454, 3·H₂O.
- copper(Ⅱ) complex;1,10-phenanthroline-5,6-dione;thiophene derivative;coupling reaction
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A Cu(Ⅱ) Complex with2,9-Dithienyl-1,10-phenanthroline-5,6-dione Ligand with Large Steric Hindrance

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通讯作者: 陈斌, bchen63@163.com

A Cu(Ⅱ) Complex with₂,9-Dithienyl^-1,10-phenanthroline-5,6-dione Ligand with Large Steric Hindrance