Citation: HUANG Chao, WU Juan, CHEN Dong-Mei, ZHANG Qi-Long, ZHU Bi-Xue. Syntheses and Crystal Structures of Cd(Ⅱ) and Zn(Ⅱ) Complexes Containing 2-Acetylpyridine-o-aminobenzoylhydrazone Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 109-113. doi: 10.11862/CJIC.2015.051 shu

Syntheses and Crystal Structures of Cd(Ⅱ) and Zn(Ⅱ) Complexes Containing 2-Acetylpyridine-o-aminobenzoylhydrazone Ligand

1.
1. Key laboratory of Macrocycle and Supramolecular Chemistry, Guizhou University, Guiyang 550025, China;
2.
2. Department of Chemistry, Guiyang Medical College, Guiyang 550004

Corresponding author: ZHU Bi-Xue,
Received Date: 22 July 2014
Available Online: 6 November 2014
Fund Project: 国家自然科学基金资助项目(No.21061003) (No.21061003)教育部"春晖计划"项目(No.132008) (No.132008)

Two complexes [CdL(NO₃)₂·H₂O] (1) and [ZnL₂] (2) were synthesized by the reaction of Schiff base ligand (2-acetylpyridine-o-aminobenzoylhydrazone) (L) with Cd(NO₃)₂·4H₂O or Zn(CH₃COO)₂·2H₂O respectively. The compounds are characterized by ¹H NMR, FTIR, and elemental analysis. The structures of the two complexes are analyzed via single crystal X-ray diffraction. The results show that the complex 1 crystallizes in monoclinic, space group P2₁/_n, and the complex 2 crystallizes in monoclinic, space group P2₁/c. The antibacterial activities of the ligand and complexes were measured in vitro, and the results show that the ligand Land complex 1 possess inhibiting effects to bacteria. CCDC: 1012633, 1; 1012634, 2.
- Schiff base;complex;crystal structure;antibacterial activity
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沈阳化工大学材料科学与工程学院沈阳 110142