Citation: JI Ke-Ming, MENG Fan-Hui, GAO Yuan, LI Zhong. Solution Combustion Prepared Ni-Based Catalysts and Their Catalytic Performance for Slurry Methanation[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 267-274. doi: 10.11862/CJIC.2015.050
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Ni-Al2O3, Ni-ZrO2, Ni-La2O3 and Ni-CeO2 catalysts were prepared by solution combustion method using Al(NO3)3, ZrO(NO3)2, La(NO3)3 and Ce(NO3)3 (mixed with Ni(NO3)2 and urea in aqueous solution) as the support precursor, respectively. The COmethanation performances of catalysts were studied in slurry-bed reactor, and the catalysts were characterized by low temperature N2 adsorption-desorption, XRD, SEM, TEM, H2-TPRand H2 chemsorption. The results show that the combustion preparation process of Ni-Al2O3 catalyst using Al(NO3)2 as the precursor is stable for long-duration(up to 23 s) and the catalyst has larger surface area (468 m2·g-1) and metal surface area (10 m2·g-1), smaller Ni particle (3~5 nm), excellent dispersion of Ni, and the catalyst has good catalytic performance, whose COconversion and CH4 selectivity are 94% and 95%, respectively, and no catalyst deactivation is observed in 100h. The preparation process for catalysts using ZrO(NO3)2 and La(NO3)3 as precursors does not show obvious flame and burning time is also shorter (12 s and 5 s), the surface areas, metal surface areas and catalytic performances are lower than that of Ni-Al2O3 while that for the catalyst using Ce(NO3)2 as the precursor has high intensity combustion. The catalyst obtained from Ce(NO3)2 precursor shows lower surface area (22 m2·g-1) and metal surface area (5 m2·g-1), larger Ni particle and worse dispersion of Ni and the worst methanation catalytic performance with COconversion and CH4 selectivity of 41% and 89%, respectively.
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-
[1]
[1] Kopyscinski J, Schildhauer T J, Biollaz S M A. Fuel, 2010,89 (8):1763-1783
-
[2]
[2] Zhang J, Bai Y, Zhang Q, et al. Fuel, 2014,132:211-218
-
[3]
[3] Gao J, Wang Y, Ping Y, et al. RSC Adv., 2012,2(6):2358-2368
-
[4]
[4] CUI Xiao-Xi(崔晓曦), FAN Hui(范辉), ZHENG Hua-Yan(郑华艳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(3):495-502
-
[5]
[5] CUI Xiao-Xi(崔晓曦), MENG Fan-Hui(孟凡会), HE Zhong (何忠), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013, 30(2):277-283
-
[6]
[6] Zhao A, Ying W, Zhang H, et al. Catal. Comun., 2012,17: 34-38
-
[7]
[7] Tada S, Shimizu T, Kameyama H, et al. Int. J. Hydrogen Energy, 2012,37(7):5527-5531
-
[8]
[8] Cai M, Wen J, Chu W, et al. J. Nat. Gas Chem., 2011,20 (3):318-324
-
[9]
[9] SONG Huan-Ling(宋焕玲), YANG Jian(杨建), ZHAO Jun(赵军), et al. Chin. J. Catal.(催化学报), 2010,31(1):21-23
-
[10]
[10] Meng F H, Zhong P Z, Li Z, et al. J. Chem, 2014,2014:1-7
-
[11]
[11] MENG Fan-Hui(孟凡会), LIU Jun(刘军), LI Zhong(李忠), et al. J. Fuel Chem. Technol.(燃料化学学报), 2014,42(2): 231-237
-
[12]
[12] Pfeil T L, Pourpoint T L, Groven L J. Int. J. Hydrogen Energy, 2014,39(5):2149-2159
-
[13]
[13] Dinka P, Mukasyan A S. J. Phys. Chem. B, 2005,109(46): 21627-21633
-
[14]
[14] Sharma S, Hu Z, Zhang P, et al. J. Catal., 2011,278(2):297-309
-
[15]
[15] Colussi S, Gayen A, Llorca J, et al. Ind. Eng. Chem. Res., 2012,51(22):7510-7517
-
[16]
[16] González-Cortés S L, Imbert F E. Appl. Catal. A, 2013,452: 117-131
-
[17]
[17] Jung C H, Jalota S, Bhaduri S B. Mater. Lett., 2005,59(19/20):2426-2432
-
[18]
[18] LU Chang(路长), ZHOU Jian-Jun(周建军), LIN Qi-Zhao(林其钊), et al. J. Combust. Sci. Technol.(燃烧科学与技术), 2005,11(1):41-46
-
[19]
[19] WU Shu-Rong(吴淑荣), XIONG Wei-Miao(熊为淼), HE Ming-An(何明安), et al. J. Northwest Univ.(西北大学学报), 1981,22(3):32-38
-
[20]
[20] Zou X, Wang X, Li L, et al. Int. J. Hydrogen Energy, 2010, 35(22):12191-12200
-
[21]
[21] Yang J, Wang X, Li L, et al. Appl. Catal. B, 2010,96(1-2): 232-237
-
[22]
[22] Koo K Y, Roh H-S, Seo Y T, et al. Int. J. Hydrogen Energy, 2008,33(8):2036-2043
-
[23]
[23] Zhang J, Xu H, Jin X, et al. Appl. Catal. A, 2005,290(1-2): 87-96
-
[24]
[24] Nagai M, Zahidul A M, Kunisaki Y, et al. Appl. Catal. A, 2010,383(1-2):58-65
-
[25]
[25] Kam R, Selomulya C, Amal R, et al. J. Catal., 2010,273(1): 73-81
-
[26]
[26] LIU Na(刘娜), DU Xia-Ru(杜霞茹), YUAN Zhong-Shan(袁中山), et al. J. Chinese Soc. Rare Earths(中国稀土学报), 2005,23(1):26-30
-
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