Citation: CHEN Yan-Min, CHU Zhao-Hua, HAO Gui-Xia, XIE Qing-Fan. Syntheses, Crystal Structures and Fluorescence Properties of a Hydrazone Schiff Base and its Zinc Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 317-322. doi: 10.11862/CJIC.2015.044 shu

Syntheses, Crystal Structures and Fluorescence Properties of a Hydrazone Schiff Base and its Zinc Coordination Polymer

1.
1. College of Chemistry and Life Science, Quanzhou Normal University, Quanzhou, Fujian 362000, China;
2.
2. Department of Chemistry, HanShan Normal University, Chaozhou, Guangdong 521041, China

Corresponding author: CHU Zhao-Hua,
Received Date: 8 October 2014
Available Online: 13 November 2014
Fund Project: 福建省教育厅A类重点项目(No.JA14261) (No.JA14261)广东省科技厅科技项目(No.2011B090400521)资助 (No.2011B090400521)

Ahydrazone Schiff base monohydrate, C₁₇H₂₀N₄O₂·H₂O (1), was synthesized by rection of 4-diethylamino -salicylaldehyde and isoniazide, and its zinc(Ⅱ) coordination polymer, [Zn(L)(Phen)]_∞ (2) with double helix structure, was prepared. They have been characterized by elemental analysis, IR, UV-vis spectra and X-ray diffraction single crystal analysis and the fluorescence property of the compounds were investigated, which result showed that the crystal of 1 belongs to the triclinic system,space group P1 with cell parameters a=0.71058(4) nm, b=1.0045(2) nm, c=1.3054(3) nm, α=97.383(11)°, β=102.989(12)°, γ=104.038(10)°, V=8.641(3) nm³, Z=2, M_r=330.39, D_c=1.270 g·cm^-3 and the crystal of 2 belongs to the trigonal system,space group P₃₂ with cell parameters a=1.68654(12) nm, b=1.68654(12) nm, c=0.79656(12) nm, V=1.9622(5) nm³, Z=3, M_r=555.93, D_c=1.411 g·cm^-3. The compounds 1 and 2 exhibit luminescence with emission maximum at 524 and 535 nm at room temperature, respectively. CCDC: 995121, 1; 994066, 2.
- zinc complex;crystal structure;fluorescence properties;salicylaldehyde;isonicotinoyl hydrazone
1. [1]
  [1] HU Zong-Zhi(胡宗志), ZHAO-Jun(赵君), KE Xi-Jun(柯希俊), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011,27 (1):184-188
2. [2]
  [2] ZHOU Xian-Li(周先礼), ZHANG Bing-Jun(张秉君), WANG Cui-Juan(王萃娟), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,27(8):1736-1742
3. [3]
  [3] Zhai Q G, Li S N, Gao X, et al. Inorg. Chem. Commun., 2010,13:211-214
4. [4]
  [4] Zaworotko M J. Nat. Chem., 2009,1:267-268
5. [5]
  [5] Ma S, Sun D, Yuan D, et al. J. Am. Chem. Soc., 2009,131: 6445-6451
6. [6]
  [6] HU Yun-Xia(胡云霞), ZHANG Wen-Wei(章文伟), LI Yi-Zhi (李一志), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(4):717-724
7. [7]
  [7] CHEN Yan-Min(陈延民), XIE Qing-Fan(解庆范), WEI Zan-Bin(魏赞斌), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(6):1243-1249
8. [8]
  [8] LI Rong(李蓉). Thesis for the Master of Tianjin University (天津大学硕士论文). 2007.
9. [9]
  [9] Xu H, Wang X, Zhang C, et al. Inorg. Chem. Commun., 2013,34:8-11
10. [10]
  [10] Sutradha M, Barman T R, Rentschler E. Inorg. Chem. Commun., 2014,39:140-143
11. [11]
  [11] ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29(7):1442-1446
12. [12]
  [12] WANG Yan(王彦), LIU Guang-Xiang(刘光祥). Chinese J. Inorg. Chem.(无机化学学报), 2009,25(4):713-719
13. [13]
  [13] CHI Yu-Xian(迟玉贤), NIU Shu-Yun(牛淑云), JIN Jing(金晶), et al. Spectrosc. Spectra. Anal.(光谱学与光谱分析), 2008,28(10):2258-2262
14. [14]
  [14] LI Xin-Wei(李欣玮), WANG Peng(王鹏), ZHAO Ying(赵营), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30 (6):1361-1366
15. [15]
  [15] Roy P, Manassero M, Dhara K, et al. Polyhedron, 2009,28: 1133-1137
16. [16]
  [16] JIANG Zheng-Jing(蒋正静), WU Ya-Mei(吴亚梅), LU Lu-De(陆路德), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(9):2119-2126
17. [17]
  [17] GU Ya-Kun(顾雅琨), QIU Xiao(邱晓), SONG Jin-Hao(宋金浩), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011,27 (6):1143-1149
18. [18]
  [18] Sheldrick G M. SHELXTL, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, Germany, 1997.
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
5. [5]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
8. [8]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
9. [9]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
10. [10]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
11. [11]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
12. [12]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
13. [13]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
14. [14]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
15. [15]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
16. [16]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
17. [17]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
18. [18]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
19. [19]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
20. [20]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(156)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142