Citation: FENG Yong-Lan, YU Jiang-Xi, KUANG Dai-Zhi, TAN Yu-Xing, ZHANG Fu-Xing, JIANG Wu-Jiu, ZHU Xiao-Ming, ZHENG Jian-Hua. Syntheses, Crystal Structures, and Anti-tumor Activity of Tetra-nuclear Cluster and 1D Chain Butyltin α-Naphthaleneacetic Carboxylates[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 710-716. doi: 10.11862/CJIC.2015.041
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The tetra-nuclear cluster dibutyltin α-naphthaleneacetic carboxylate {[n-Bu2Sn(O2CCH2C10H7)]2O}2 (1) and the 1D chain tributyltin α-naphthaleneacetic carboxylate [n-Bu3Sn(O2CCH2C10H7)]n (2) were synthesized by the reactions of α-naphthaleneacetic acid with dibutyltin oxide and bis(tributyltin) oxide under the same conditions, respectively. Their structures were characterized by IR, 1H and 13C NMR, elemental analysis and X-ray crystal diffraction. The core structures of 1 are two Sn2O2 four-membered rings which are constructed of Sn atoms with O bridges, and the two Sn2O2 units are dimerized to a Sn4O4 cluster, so the center of central Sn2O2 ring coincides with the symmetry center of whole molecule. Due to the C-H…π interactions, the adjacent molecules of complex 1 is linked to generate 1D ribbon structure. For complex 2, two Sn atoms are bridged by two O atoms of a carboxylate ligand to form 1D infinite chain coordination polymer. Thermogravimetric analysis shows the complexes were stable up to 250 or 175℃, respectively. Moreover, the tests showed that both of them displayed strong in vitro anti-tumor activity against five human tumor cell lines, Colo205, HepG2, MCF-7, Hela and NCI-H460, but the activity order is 2 >1. CCDC: 1026774, 1; 1026775, 2.
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