Citation: LI Guo-Feng, WANG Ya-Nan, WANG Qing-Wei, LI Xiu-Mei, JI Jian-Ye, PAN Ya-Ru. Syntheses and Crystal Structures of Two Complexes of Manganese, Cobalt Assembled by5-Nitroisophthalic Acid and Bis(imidazol) Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 183-190. doi: 10.11862/CJIC.2015.034
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Two new complex [Mn(NIPH)(mbix)]n (1) and [Co(NIPH)(mbix)(H2O)3]2n·2nH2O (2) (H2NIPH=5-nitroiso-phthalic acid, mbix=1,3-bis(imidazol-1-ylmethyl)benzene) have been hydrothermally synthesized and structurally characterized by elemental analysis, IRspectrum, UVspectrum, TGand single-crystal X-ray diffraction. They are further extended into a three-dimensional supramolecular network structure through hydrogen bonds and π-π interactions. CCDC: 979616, 1; 1011701, 2.
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