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Citation: CHEN Yan-Min, XIE Qing-Fan, LIU Jin-Hua, HE Xue-Qian, ZHANG Qiong-Ru. Syntheses, Crystal Structures and Properties of Nickel(Ⅱ) and Copper(Ⅱ) Complexes with2-Acetylpyridine Isonicotinoyl Hydrazone Schiff Base[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 74-80. doi: 10.11862/CJIC.2015.033 shu

Syntheses, Crystal Structures and Properties of Nickel(Ⅱ) and Copper(Ⅱ) Complexes with2-Acetylpyridine Isonicotinoyl Hydrazone Schiff Base

  • 1.

    College of Chemistry & Life Science, Quanzhou Normal University, Quanzhou, Fujian 362000, China

  • Corresponding author: XIE Qing-Fan, 
  • Received Date: 27 June 2014
    Available Online: 22 September 2014

    Fund Project: 泉州师范学院学科建设资金和国家级大学生创新创业训练计划项目(201310399018)资助 (201310399018)

  • The nickel(Ⅱ) and copper(Ⅱ) complexes [NiL2] (1) and [Cu(Ac)L] (2) were synthesized by reaction of 2-acetylpyridine isonicotinoyl hydrazone Schiff base(HL) with metal acetate, and characterized by elemental analysis, IR, UV-Vis, FLspectra, TGA and X-ray crystal diffraction. The crystal of 1 belongs to the orthorhombic system,space group Aba2 with cell parameters a=1.2059 (3) nm, b=2.0741(5) nm, c=0.9115 (2) nm, V=2.2798 (10) nm3, Z=4, Mr=537.21, Dc=1.565 g·cm-3, F(000)=1113 and the crystal of 2 belongs to the monoclinic system,space group P21/c with cell parameters a=0.86477(13) nm, b=1.3383(2) nm, c=1.3631(2) nm, β=105.650 (4)°, V=1.5190(4) nm3, Z=4, Mr=361.85, Dc=1.582 g·cm-3, F(000)=740. The tests showed the two complexes displayed good thermal stability below 340 ℃(1)和296 ℃(2), respectively. The complexes exhibits blue luminescence with emission maximum at 430 and 428 nm at room temperature, respectively. CCDC: 952992, 1; 993273, 2.
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    1. [1]

      [1] LONG Yun-Fei(龙云飞), CAI Tie-Jun(蔡铁军), CHENG Meng-Qi(程孟奇), et al. Chinese J. Appl. Chem. (应用化 学), 2003,7(1):125-127

    2. [2]

      [2] JIANG Yi-Min(蒋毅民), ZHANG Shu-Hua(张淑华), XU Qing(徐庆), et al. Acta Chim. Sinica (化学学报), 2003,61 (4):573-577

    3. [3]

      [3] WANG Ming-Ming(王明明), XIE A-Gui(谢阿贵), WANG Hui(王慧), et al. Chinese J. Inorg. Chem. (无机化学学报), 2009,25(5):942-945

    4. [4]

      [4] Bazzicalupi C, Bencini A, Bianchi A, et al. Coord. Chem. Rev., 2008,252:1052-1068

    5. [5]

      [5] Pouralimardan O, Chamayou A C, Janiak C, at al. Inorg. Chim. Acta, 2007,360:1599-1608

    6. [6]

      [6] Yu T Z, Su W M, Li W L, et al. Inorg. Chim. Acta, 2006,359:22462251

    7. [7]

      [7] HUO Yong-Qian(霍涌前), WANG Sheng-Wen(王升文), CUI Hua-Li(崔华莉), et al. Chinese J. Inorg. Chem. (无机化学 学报), 2010,26(7):1274-1278

    8. [8]

      [8] WANG Yan(王彦), LIU Guang-Xiang(刘光祥). Chinese J. Inorg. Chem. (无机化学学报), 2009,25(4):713-719

    9. [9]

      [9] Ainscough E W, Brodie A M, Dobbs A J, et al. Inorg.Chim. Acta, 1998,267:27-38

    10. [10]

      [10] HU Zong-Qiu(胡宗球), DING Yu(丁瑜), JIA Bing(加兵), et al. Chinese J. Inorg. Chem. (无机化学学报), 2006,22(5): 925-929

    11. [11]

      [11] DAI Mei-Bi(戴美碧), ZHANG Qi-Long(张奇龙), ZHU Bi-Xue(朱必学), et al. Chinese J. Inorg. Chem. (无机化学学 报), 2008,24(9):l381-1386

    12. [12]

      [12] WU Qiong-Jie(吴琼洁), CHEN Xiao-Hua(陈小华), CAI Bi-Qiong(蔡碧琼), et al. Chinese J. Inorg. Chem. (无机化学学 报), 2012,28(1):201-206

    13. [13]

      [13] Richardson D R, Becker E, Bernhardt P V. Acta Crystallogr., 1999,C55:2102-2105

    14. [14]

      [14] LI Geng(李庚), YAN Wen-Bo(阎文波), HE Cheng(何成), et al. Chinese J. Inorg. Chem.(无机化学学报), 2008,24(11): 1767-1771

    15. [15]

      [15] HUANG Zhi-Wei(黄志伟), LIU Xing(刘星), LI Zhong-Liang(黎中良). Chem. Res. Appl.(化学研究与应用), 2011, 23(4):457-461

    16. [16]

      [16] WANG Jing-Lin(王景琳), JIAO Yong(焦勇), YANG Bin-Sheng(杨斌盛). Chinese J. Inorg. Chem. (无机化学学报), 2014,30(2):411-418

    17. [17]

      [17] Chaur M N. Acta Crystallogr., 2013,E69:m27

    18. [18]

      [18] Sy A, Dieng M, Thiam I E, et al. Acta Crystallogr., 2013, E69:m108

    19. [19]

      [19] DENG Ji-Hua(邓记华), YU Qing(于青), BIAN He-Dong (边贺东), et al. J. Guangxi Normal University: Natural Science Edition(广西师范大学学报:自然科学版), 2006,24 (1):60-63

    20. [20]

      [20] ZHENG Chang-Zheng(郑长征), WANG Yan-Yan(王燕燕), WANG Liang(王亮). Chinese J. Inorg. Chem. (无机化学学 报), 2014,30(7):1474-1480

    21. [21]

      [21] WANG Hui(王慧), GAN Guo-Qing(甘国庆), QU Yang (瞿阳), et al. Chinese J. Inorg. Chem. (无机化学学报), 2012,28(6):1217-1221

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