Citation: XU Feng-Qin, HU Xiao-Fei, CHENG Fang-Yi, LIANG Jing, TAO Zhan-Liang, CHEN Jun. Preparation of Porous Carbon-Supported Ni Nanoparticles for Catalytic Hydrogen Generation from Ammonia Borane Hydrolysis[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 103-108. doi: 10.11862/CJIC.2015.032
-
Honeycomb-like hierarchical porous carbon was prepared and employed as substrate to support nickel nanparticles via an impregnation-chemical reduction method. The synthesized carbon-supported nickel (denoted as Ni/C) was used as catalysts for hydrogen generation from hydrolysis of ammonia borane (AB). Results of XRD, BET, SEM, Raman, and TEM measurements showed that the synthesized carbon possessed high specific surface area of 737 m2·g-1 and partially graphited structure; the supported amorphous Ni nanoparticles had an average particle size of 10 nm and were uniformly dispersed on the porous carbon substrate. The synthesized Ni/C exhibited high catalytic activity towards the hydrolysis of AB. At hydrolysis temperature of 298 K, Ni/C with 30wt% Ni loading was the most active, resulting in a high hydrogen release rate of 1304.67 mL·min-1·g-1 and a low activation energy of 29.1 kJ·mol-1. In addition, the Ni/C catalyst could be repeatedly utilized with respectable activity reservation for several times. The results indicate that Ni/C is a promising low-cost catalyst for hydrolytic dehydrogenation of AB.
-
-
[1]
[1] Liu C, Fan Y Y, Liu M, et al. Science, 1999,286:1127-1129
-
[2]
[2] TANG Xiao-Ming(唐晓鸣), LIU Ying-Liang(刘应亮). Chinese J. Inorg. Chem.(无机化学学报), 2001,17(2):161-167
-
[3]
[3] Yang L, Su J, Luo W, et al. Int. J. Hydrogen Energy, 2014, 39:3360-3370
-
[4]
[4] Zhang T R, Yang X J, Yang S Q, et al. Phys. Chem. Chem. Phys., 2011,13:18592-18599
-
[5]
[5] Yang X J, Cheng F Y, Liang J, et al. Int. J. Hydrogen Energy, 2009,34:8785-8791
-
[6]
[6] WU Guo-Tao(吴国涛), CHEN Wei-Dong(陈维东), XIONG Zhi-Tao(熊智涛). Chinese Journal of Nature(自然杂志), 2011,33(1):27-34
-
[7]
[7] ZOU Shao-Shuang(邹少爽), TAO Zhan-Liang(陶占良), CHEN Jun(陈军). Acta Chim. Sinica(化学学报), 2011,69(18):2117-2122
-
[8]
[8] TAO Zhan-Liang (陶占良), PENG Bo(彭博), LIANG Jing(梁 静), et al. Materials China(中国材料进展), 2009,28(Z1):26-40
-
[9]
[9] Graham T W, Tsang C W, Chen X H, et al. Angew. Chem. Int. Ed., 2010,49:8708-8711
-
[10]
[10] HUANG Ren-Zhong(黄仁忠), YANG Wen-Jing(杨文静), LIU Liu(刘柳), et al. Journal of Shenyang Normal University: Natural Science(沈阳师范大学学报:自然科学版), 2011, 29(3):395-398
-
[11]
[11] Cao N, Su J, Luo W, et al. Int. J. Hydrogen Energy, 2014, 39:426-435
-
[12]
[12] Yang X J, Cheng F Y, Tao Z L, et al. J. Power Sources, 2011,196:2785-2789
-
[13]
[13] Luo W, Campbell P G, Zakharov L N, et al. J. Am. Chem. Soc., 2011,133:19326-19329
-
[14]
[14] Chandra M, XU Q. J. Power Sources, 2007,168:135-142
-
[15]
[15] Zhao J Z, Ma H, Chen J. Int. J. Hydrogen Energy, 2007,30: 4711-4716
-
[16]
[16] Umegaki T, Yan J M, Zhang X B, et al. Int. J. Hydrogen Energy, 2009,34:3816-3822
-
[17]
[17] Li P Z, Aijaz A, Xu Q. Angew. Chem. Int. Ed., 2012,51: 6753-6756
-
[18]
[18] Du J, Cheng F Y, Si M, et al. Int. J. Hydrogen Energy, 2013,38:5768-5774
-
[19]
[19] Cao N, Luo W, Cheng G Z. Int. J. Hydrogen Energy, 2013, 38:11964-11972
-
[20]
[20] Yang X J, Cheng F Y, Liang J, et al. Int. J. Hydrogen Energy, 2011,36:1984-1990
-
[21]
[21] Yan J M, Zhang X B, Han S, et al. Inorg. Chem., 2009,48: 7389-7393
-
[22]
[22] Umegaki T, Yan J M, Zhang X B, et al. J. Power Sources, 2009,191:209-216
-
[23]
[23] WU Xue-Yan(吴雪艳), WANG Kai-Xue(王开学), CHEN Jie-Sheng(陈接胜). Prog. Chem.(化学进展), 2012,24(Z1): 262-274
-
[24]
[24] CHENG Ji-Peng(程继鹏), ZHAN Xiao-Bin(张孝彬). Chinese J. Inorg. Chem.(无机化学学报), 2006,22(5):967-970
-
[25]
[25] Qiu F Y, Li L, Liu G, et al. Int. J. Hydrogen Energy, 2013, 38:3041-3049
-
[26]
[26] Zhao J Z, Cheng F Y, Yi C H, et al. J. Mater. Chem., 2009, 19:4108-4116
-
[27]
[27] Yamada H, Nakamura H, Nakahara F, et al. J. Phys. Chem. C, 2007,111:227-233
-
[28]
[28] Kruk M, Jaroniec M. Chem. Mater., 2001,13:3169-3183
-
[29]
[29] Tuinstra F, Koenig J. J. Chem. Phys., 1970,53:1126-1130
-
[30]
[30] Ozaya O, Ingerb E, Aktasc N, et al. Int. J. Hydrogen Energy, 2011,36:8209-8216
-
[1]
-
-
[1]
Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
-
[2]
Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
-
[3]
Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H2 production activity of BaTiO3 nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
-
[4]
Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
-
[5]
Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
-
[6]
Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
-
[7]
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
-
[8]
Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
-
[9]
Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
-
[10]
Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
-
[11]
Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
-
[12]
Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
-
[13]
Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C60-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
-
[14]
Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
-
[15]
Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
-
[16]
Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO2 methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
-
[17]
Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO2/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
-
[18]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(465)
- HTML views(45)