Citation: ZHANG Jun-Min, TAN Zhi-Long, WANG Chuan-Jun, BI Jun, YI Wei, SHENG Yue, GUAN Wei-Ming, WEN Ming. Effect of Carbon Support Pretreatment on Structure and Performance of Pt/C Electrocatalysts[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 140-146. doi: 10.11862/CJIC.2015.022 shu

Effect of Carbon Support Pretreatment on Structure and Performance of Pt/C Electrocatalysts

1.
State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China

Corresponding author: WEN Ming,
Received Date: 12 August 2014
Available Online: 20 October 2014
Fund Project: 国家地区科学基金(No.51262015) (No.51262015)云南省基金(No.2011FB125)资助项目. (No.2011FB125)

Pt/C catalysts were prepared using a new modified polyol method with different heat treatment temperatures of Vulcan XC-72 carbon support. The oxygen containing functional group and the specific surface area of carbon black were characterized by pH meter and physical adsorption instrument. The composition, morphology and the electrochemical properties of the Pt/C catalyst were characterized by coupled plasma atomic emission spectroscopy, Transmission electron microscopy, X-ray diffraction and cyclic voltammograms, respectively. The results indicate that the Pt/C catalyst with 400 ℃ heat treatment for carbon black has an electrochemical specific surface area of 83 m²·g^-1, and the quality of the current density of 49.03 A·g^-1, while the corresponding parameters for imported commercial JM 20% Pt/C catalyst are 77 m²·g^-1 and 11.13 A·g^-1, respectively. The Pt loading in the present work is decreased by 3wt%~4wt% and the electric catalytic activity for the catalyst obtained in this work is better than that of commercial JM 20% Pt/C catalyst.
- catalysis;catalysts;Pt/C;carbon black;microstructure
1. [1]
  [1] YI Bao-Lian(衣宝廉). Fuel Cell Efficiency, Environmental Friendly Generator(燃料电池-高效,环境友好的发电方式). Beijing: Chemical Industry Press, 2000:302
2. [2]
  [2] YI Bao-Lian(衣宝廉). Fuel Cell: Principle, Technology, Application(燃料电池-原理·技术·应用). Beijing: Chemical Industry Press, 2003:289
3. [3]
  [3] Lee J Y, Yun Y H, Park S W, et al. Microporous Mesoporous Mater., 2010,35(1):1-7
4. [4]
  [4] Zhou W, Zhou Z, Song S, et al. Appl. Catal. B, 2003,46(3): 273-285
5. [5]
  [5] Jung Ju Hae , Park Hyang Jin, Kim Junbom, et al. J. Power Sources, 2014,248(2):1156-1162
6. [6]
  [6] Shao Y Y, Yin G P, Wang J J, et al. J. Power Sources, 2006, 161(3):47-53
7. [7]
  [7] Gasteiger H A, Kocha S S, et al. Appl. Catal. B: Environ., 2005,56(4):9-35
8. [8]
  [8] Liang D, Gao J, Wang J H, et al. Catal. Commun., 2009,10 (12):1586-1590
9. [9]
  [9] Liang D, Gao J, Sun H, et al. Appl. Catal. B: Environ., 2011, 106(3):423-432
10. [10]
  [10] ZHANG Jun-Min(张俊敏), ZHU Fang-Fang(朱芳芳), LIU Wei-Ping(刘伟平), et al. Rare Metal Mater. Eng.(稀有金属材料与工程), 2013,42(9):1941-1944
11. [11]
  [11] Sheng E, Bradley R H, Freakley P K. J. Mater. Sci., 1996, 30(21):5651-5655
12. [12]
  [12] Park S J, Kim J S. J. Adhes. Sci. Technol., 2001,15(12): 1443-1452
13. [13]
  [13] WANG Dao-Hong(王道宏), ZHANG Ji-Yan(张继炎), WANG Ri-Jie(王日杰),et al. J. Tianjin University(天津大学学报), 2004,37(1):10-14
14. [14]
  [14] Kinoshita K. Carbon: Electrochemical and Physicochemical Properties. New York: Wiley Chichester, 1988:385
15. [15]
  [15] ZHOU Zhi-Min(周志敏), SHAO Zhi-Gang(邵志刚), YI Bao- Lian(衣宝廉). Battery(电池), 2009,39(4):177-180
16. [16]
  [16] ZENG Li-Zen(曾丽珍), LI Wei(李伟), LI Wei-Shan(李伟善). The 26th Annual Meeting of The New Energy and Chemical Breakout Anthology, Chinese Chemical Society(中国化学会第26届学术年会新能源与能源化学分会场论文集). Tianjin, 2008:567-572
17. [17]
  [17] ZHOU Hong-Ru(周红茹), TANG Hou-Wen(唐厚闻), CHEN Xue-Song(陈雪松), et al. Shanghai Auto(上海汽车), 2013, 10(7):6-8
1. [1]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
2. [2]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
3. [3]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
4. [4]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
5. [5]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
6. [6]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
7. [7]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
8. [8]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
9. [9]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
10. [10]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
11. [11]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
12. [12]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
13. [13]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
14. [14]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
15. [15]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
16. [16]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
17. [17]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
18. [18]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
19. [19]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
20. [20]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(395)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142