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Citation: HU Guo-Rong, LU Wei, LIANG Long-Wei, CAO Yan-Bing, PENG Zhong-Dong, DU Ke. Ni, Mn-Codoped High-Voltage LiCoO2 Cathode Material for Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 159-165. doi: 10.11862/CJIC.2015.020 shu

Ni, Mn-Codoped High-Voltage LiCoO2 Cathode Material for Lithium Ion Batteries

  • 1.

    School of Metallurgy and Environment, Central South University, Changsha, Hunan 410083, China

  • Corresponding author: DU Ke, 
  • Received Date: 29 August 2014
    Available Online: 23 October 2014

    Fund Project: 国家自然科学基金(No)资助项目. (No)

  • The precursor Co0.9Ni0.05Mn0.05(OH)2 of the high-voltage cathode material for lithium ion batteries was synthesized by hydroxide co-precipitation method using the transition metal sulphate as the raw material, NaOH and NH3·H2Oas the precipitate agents. Then the corresponding Li(Co0.9Ni0.05Mn0.05)O2 was obtained when mixing the precursor with Li2CO3 by high solid method. Crystal structure, morphology and electrochemical performance of the sample were investigated by XRD, SEM, Cyclic voltammetry (C-V) method, electrochemical impedance spectroscopy (EIS) test and charge-discharge test. Mixed doping Ni-Mn material Li(Co0.9Ni0.05Mn0.05)O2 shows better electrochemical performance compared to LiCoO2 as confirmed by the results of C-V, XRD and EIS. When the co-doped product Li(Co0.9Ni0.05Mn0.05)O2 was charged to 4.4 and 4.5 V, the initial discharge capacity is 162.5 mAh·g-1 and 185 mAh·g-1 at 0.5Crate, respectively. After cycling for 100 times, the retention of discharge capacity was 94.4% and 93.7%, respectively.
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