Citation: WANG Jian-Qiu, ZHANG Fu-Xing, KUANG Dai-Zhi, FENG Yong-Lan, YU Jiang-Xi, JIANG Wu-Jiu, ZHU Xiao-Ming. Syntheses, Crystal Structures and Quantum Chemistry of Tri(3,5-dimethylbenzyl)tin Chloride and Tetra(m-cyanobenzyl)tin[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 237-242. doi: 10.11862/CJIC.2015.018 shu

Syntheses, Crystal Structures and Quantum Chemistry of Tri(3,5-dimethylbenzyl)tin Chloride and Tetra(m-cyanobenzyl)tin

1.
Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: ZHANG Fu-Xing,
Received Date: 19 June 2014
Available Online: 20 October 2014
Fund Project: 湖南省高校创新平台开放基金项目(No.12K124) (No.12K124)湖南省自然科学基金项目(No.11JJ3021) (No.11JJ3021)湖南省重点学科基金和湖南省高校重点实验室开放基金(No.13K02)资助 (No.13K02)

The tri(3,5-dimethylbenzyl)tin chloride (1) and the tetra(m-cyanobenzyl)tin (2) have been synthesized. The crystal structures of the complexes were determined by X-ray diffraction. The crystal of 1 belongs to monoclinic space group P2₁/m with a=0.58403(4) nm, b=1.96637(14) nm, c=0.85646(5) nm, β=95.138(3)°, V=0.97962(11) nm³, Z=2, D_c=1.735 g·cm^-3, μ(Mo Kα)=14.53 cm^-1, F(000)=524, R₁=0.0437, wR₂=0.1232. The crystal 2 belongs to monoclinic space group C2/c with a=1.69221(12) nm, b=1.16741(8) nm, c=1.53941(11) nm, β=116.615(10)°, V=2.7189(3) nm³, Z=4, D_c=1.424 g·cm^-3, μ(Mo Kα)=9.67 cm^-1, F(000)=1176, R₁=0.0175, wR₂=0.0461. The tin atoms have a distorted tetrahedral geometry. The stabilities, some frontier molecular orbital energies and composition characteristics of some frontier molecular orbital of the complex have been investigated by quantum chemistry calculation. CCDC: 1030252, 1; 1030251, 2.
- tri(3,5-dimethylbenzyl)tin chloride;tetra(m-cyanobenzyl)tin;synthesis;crystal structure
1. [1]
  [1] Chandrasekhar V, Thirumoorthi R, Metre R K, et al. J. Organomet. Chem., 2011,696:600-606
2. [2]
  [2] Effendy, Marchetti F, Marinelli A, et al. J. Inorg. Chem. Acta, 2011,366:388-393
3. [3]
  [3] Hanif M, Hussain M, Ali S, et al. Polyhedron, 2010,29:613-619
4. [4]
  [4] ZHANG Xiao-Yan(张晓燕), YANG Guang(杨光), ZHANG Jun(张俊), et al. Chem. J. Chinese Universities(高等学校化学学报), 2010,31(6):1162-1166
5. [5]
  [5] Siddiqi Z A, Shahid M, Kumar S, et al. J. Organomet. Chem., 2009,694:3768-3774
6. [6]
  [6] YIN Han-Dong(尹汉东), GAO Zhong-Jun(高中军), XU Hao-Long(徐浩龙), et al. Chinese J. Inorg. Chem.(无机化学学报), 2006,22(2):371~374
7. [7]
  [7] YIN Han-Dong(尹汉东), HONG Mei(洪敏), WANG Chuan-Hua(王传华). Chinese J. Inorg. Chem.(无机化学学报), 2005,21(5):713~715
8. [8]
  [8] ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem. (无机化学学报), 2004,20(2):202~204
9. [9]
  [9] WANG Jian-Qiu(王剑秋), ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), et al. Chinese J. Org. Chem.(有机化学), 2004,24(1):80~84
10. [10]
  [10] ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), et al. Chinese J. Org. Chem.(有机化学), 2003,23(4):368~371
11. [11]
  [11] ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), XU Zhi-Feng(许志锋), et al. Chinese J. Inorg. Chem.(无机化学学报), 2002,18(8):854~858
12. [12]
  [12] WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), ZHANG Fu-Xing(张复兴), et al. Chinese J. Inorg. Chem. (无机化学学报), 2003,19(10):1109~1112
13. [13]
  [13] YIN Han-Dong(尹汉东), GAO Zhong-Jun(高中军), XU Hao-Long(徐浩龙), et al. Chinese J. Inorg. Chem.(无机化学学报), 2005,11(21):1743-1746
14. [14]
  [14] Sheldrick G M. SHELXTL, Version 5.03. Madison, Wisconsin, USA: Siemens Analytical X-ray Division, 1994.
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
8. [8]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
9. [9]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
10. [10]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
11. [11]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
12. [12]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
13. [13]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
14. [14]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
15. [15]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
16. [16]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
17. [17]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
18. [18]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
19. [19]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
20. [20]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(95)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142