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Citation: ZHANG Chun-Li, WANG Hong-Yan, QIN Ling, ZHENG He-Gen. Syntheses, Crystal Structures and Properties of Two Co(Ⅱ) Coordination Polymers Based on1,3-Bis(imidazol-1-yl)benzene and m-Phthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 303-308. doi: 10.11862/CJIC.2015.015 shu

Syntheses, Crystal Structures and Properties of Two Co(Ⅱ) Coordination Polymers Based on1,3-Bis(imidazol-1-yl)benzene and m-Phthalic Acid

  • 1.

    1. School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Anhui 234000, China;

  • 2.

    2. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China

  • Corresponding author: ZHENG He-Gen, 
  • Received Date: 26 September 2014
    Available Online: 31 October 2014

    Fund Project: 国家重点基础研究发展计划(No.2010CB923303) (No.2010CB923303)国家自然科学基金(No.21371092) (No.21371092)宿州学院自旋电子与纳米材料安徽省重点实验室开放课题(No.2014YKF51) (No.2014YKF51)安徽高校省级自然科学研究重点项目(No.KJ2013A244、KJ2011A260) (No.KJ2013A244、KJ2011A260)安徽省自然科学基金(No.1408085MB40)资助项目. (No.1408085MB40)

  • Two coordination polymers {[Co(1,3-bib)(MPA)(H2O)2]·H2O}n (1) and {[Co2(1,3-bib)2(MPA)2]·5H2O}n (2) based on mixed-ligands, 1,3-bib(1,3-bib =1,3-bis(imidazol-1-yl)benzene) and H2MPA (H2MPA=m-phthalic acid) have been synthesized by mild hydrothermal method and characterized by elemental analysis, IRspectra, TGA, and their crystal structure was determined by single-crystal X-ray diffraction. The coordination polymer 1 crystallizes in the orthorhombic system, space group Pnma and features a 1Dstructure. The coordination polymer 2 crystallizes in the triclinic system, space group P1 and features a dual-core 2Dstructure. Ultraviolet spectroscopy studies revealed that the complexes exhibits ultraviolet absorption in the solid state at room temperature. CCDC: 954321, 1; 1023812, 2.
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