Citation: LIANG Shao-Wei, ZHONG Wei, ZHAN Cai-Xia, ZHAO Jia, LI Wen-Qiang, YE Ping, WANG Hong-Dan, SHEN Jie, FAN Lu, XIAO Zhi-Yin, LIU Xiao-Ming. Synthesis and Characterization of [FeFe]-Hydrogenase Model Complex Functionalized Polymers Based on Different Content of Alkaline Group[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 87-96. doi: 10.11862/CJIC.2015.011 shu

Synthesis and Characterization of [FeFe]-Hydrogenase Model Complex Functionalized Polymers Based on Different Content of Alkaline Group

LIANG Shao-Wei ¹ ,
ZHONG Wei ¹ ,
ZHAN Cai-Xia ² ,
ZHAO Jia ² ,
LI Wen-Qiang ² ,
YE Ping ¹ ,
WANG Hong-Dan ¹ ,
SHEN Jie ¹ ,
FAN Lu ¹ ,
XIAO Zhi-Yin ¹ ,
LIU Xiao-Ming ^1,2,,

1.
1. College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China;
2.
2. Department of Chemistry, Nanchang University, Nanchang, 330031, China

Corresponding author: LIU Xiao-Ming,
Received Date: 8 July 2014
Available Online: 18 September 2014
Fund Project: 国家级大学生创新训练计划项目(No.201310354021) (No.201310354021)国家自然科学基金(No.21171073)资助项目 (No.21171073)

Co-polymerization of [2Fe2S] model complex [Fe₂(μ-SCH₂C≡CH)₂(CO)₆] (A), diazide 2,6-(N₃CH₂)Py (B, Py=pyridine) and diyne compound (2-PyCH₂)N(CH₂C≡CH)₂ (C, Py=pyridine) led to the formation of six functionalized Polymers Polymer-1~Polymer-6 via "click reaction" by varying the ratio of the three components. These Polymers were characterized by IR spectroscopy, sulfur elemental analysis, thermal gravimetric analysis, scanning electron microscopy and electrochemistry. IR spectroscopic data and electrochemical investigations suggested that diiron hexacarbonyl complex A exists as diiron pentacarbonyl unit in these Polymers. In the co-polymerizing process, increasing the content of monomer C can significantly change the morphologies of these Polymers and improve their solubility in organic solvents and thermal stability. Electrochemistry of these Polymers in acetic acid-DMF indicated that the secondary coordination atmosphere established by introducing alkaline group provided by the monomer C can significantly enhance the catalytic performance of the diiron units in these Polymers.
- [FeFe]-hydrogenase;polymer;catalysis;Co-polymerization;"click" chemistry
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