Citation: ZHAO Xin-Hong, WEN Juan-Juan, CHEN Jing, ZHAO Jiang-Bo, QI Yong-Dong, LI Gui-Xian. Ionothermal Synthesis of Hierarchical Structured CuAPO-5 Molecular Sieve[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 29-36. doi: 10.11862/CJIC.2015.003
-
Hierarchical structured CuAPO-5 molecular sieve has been ionothermally synthesized by microwave irradiation and using eutectic mixture based on succinic acid, choline chloride and tetraethyl ammonium bromide as solvent and template. The effects of the ratio of P2O5/Al2O3, HF/Al2O3 and CuO/Al2O3, aluminum and copper sources on the crystallization of CuAPO-5 were systematically investigated. The resulting CuAPO-5 molecular sieve was characterized by X-ray diffraction (XRD), Scanning electron microscope (SEM), Transmission electron microscopy (TEM), and N2 physical adsorption-desorption, respectively. SEM analysis reveals that CuAPO-5 molecular sieve with hexagonal nanometer-disc morphology can be synthesized under specific synthesis conditions. N2 physisorption, SEM and TEM characterizations show that the resultant material is one kind of hierarchical structured aluminophosphate molecular sieve possesses both micropore and mesopore.
-
-
[1]
[1] XU Ru-Ren(徐如人), PANG Wen-Qin(庞文琴), YU Ji-Hong (于吉红), et al. Chemistry-Zeolites and Porous Materials(分 子筛与多孔材料化学). Beijing: Science Press, 2004:15-19
-
[2]
[2] Chen L H, Tang Y, Xiao F S, et al. J. Mater. Chem., 2012, 22:17381-17403
-
[3]
[3] Hua Z L, Zhou J, Shi J L. Chem. Commun., 2011,47(38): 10536-10547
-
[4]
[4] Naydenov V, Tosheva L, Antzutkin O N, et al. Microporous Mesoporous Mater., 2005,78(2/3):181-188
-
[5]
[5] Egeblad K, Kustova M, Klitgaard S K, et al. Microporous Mesoporous Mater., 2007,101(1/2):214-223
-
[6]
[6] Yang X M, Lu T L, Chen C, et al. Microporous Mesoporous Mater., 2011,144(1/2/3):176-182
-
[7]
[7] Choi M, Srivastava R, Ryoo R. Chem. Commun., 2006(42): 4380-4382
-
[8]
[8] Kim J, Bhattacharjee S, Ahn W S, et al. New J. Chem., 2010,34(12):2971-2978
-
[9]
[9] Danilina N, Krumeich F, van Bokhoven J A. J. Catal., 2010, 272(1):37-43
-
[10]
[10] Fan Y, Xiao H, Shi G, et al. J. Catal., 2012,285(1):251-259
-
[11]
[11] Alicia M S, Manuel S S, Pedro M G, et al. Microporous Mesoporous Mater., 2010,131(1/2/3):331-341
-
[12]
[12] Kanchana U, Sujitra W. Microporous Mesoporous Mater., 2010,135(1/2/3):116-123
-
[13]
[13] Zhao X H, Chen J, Sun Z P, et al. Microporous Mesoporous Mater., 2013,182:8-15
-
[14]
[14] Dang T T H, Zubowa H L, Bentrup U, et al. Microporous Mesoporous Mater., 2009,123:209-220
-
[15]
[15] HE Ye(何月), DONG Mei(董梅), Li Jun-Fen(李俊汾), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2010,26(5):1305-1310
-
[16]
[16] Wan Y, Williams C D, Duke C V A, et al. J. Mater. Chem., 2000,10:2857-2862
-
[17]
[17] Zhao X H, Wang H, Li G X, et al. Microporous Mesoporous Mater., 2012,151:56-63
-
[18]
[18] Wragg D S, Slawin A M Z, Morris R E. Solid State Sci., 2009, 11(2):411-416
-
[19]
[19] Oliver S, Kuperman A, Ozin G A. Angew. Chem., Int. Ed. Engl., 1998,37(1/2):46-62
-
[20]
[20] Hentit H, Bachari K, Ouali M S, et al. J. Mol. Catal. A: Chem., 2007,275(1/2):158-166
-
[21]
[21] Tian D Y, Yan W F, Cao X J, et al. Chem. Mater., 2008,20: 2160-2164
-
[22]
[22] Tian D Y, Yan W F, Wang Z X, et al. Cryst. Growth Des., 2009,9(3):1411-1414
-
[23]
[23] Danilina N, Castelanelli S A, Troussard E, et al. Catal. Today, 2011,168(1):80-85
-
[24]
[24] Murthy K, Kulkarni S J, Masthan S K. Microporous Mesoporous Mater., 2001,43(2):201-209
-
[1]
-
-
[1]
Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
-
[2]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[3]
Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
-
[4]
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
-
[5]
Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
-
[6]
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
-
[7]
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
-
[8]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[9]
Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag3PO4/C3N5 Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
-
[10]
Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C3N4/Ti3C2Tx Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
-
[11]
Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO2 mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
-
[12]
Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
-
[13]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[14]
Aimin Fu , Chunmei Chen , Qin Li , Nanjin Ding , Jiaxin Dong , Yu Chen , Mengsha Wei , Weiguang Sun , Hucheng Zhu , Yonghui Zhang . Niduenes A−F, six functionalized sesterterpenoids with a pentacyclic 5/5/5/5/6 skeleton from endophytic fungus Aspergillus nidulans. Chinese Chemical Letters, 2024, 35(9): 109100-. doi: 10.1016/j.cclet.2023.109100
-
[15]
Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
-
[16]
Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO3 for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
-
[17]
Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
-
[18]
Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
-
[19]
Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
-
[20]
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(527)
- HTML views(88)