Citation: YANG Rui-Huan, ZHANG Chi, HUO Ji-Chuan, QU Peng. Preparation and Study of a Novel Glucoside Aromatic Ester Based Metal Organic Material[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1073-1078. doi: 10.11862/CJIC.2014.180
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Dentate organic ester ligandsmethyl glucoside aromatic ester based ligands (MGAE ligand) (C15H18O9, C15H16O8, C22H30O14, C23H22O12, C31H26O15 or C39H30O18) with complexation ability were, through the catalysis of triethylamine, synthesized using methyl glucoside and phthalic anhydride as selected raw materials. Then, a series of MGAE ligand based metal-organic coordination compounds were prepared in the involvement of triethylamine as a template agent through complexing the new type of organic ligands with metal salt solution,Then the MGAE ligand based complexes were characterized using FT-IR, XRD, TGA, FSEM, EDS and BET. The results showed that the complexation is chiefly due to the involvement of carbonyl in the MGAE ligand and the performance of complexes is mainly influenced by the MGAE ligands and metal cations.
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