Citation: YANG Xiao, A M Showkot Hossain, ZHU Yu, MENG Su-Ci, XIA Chang-Kun, XIE Ji-Min. Syntheses, Crystal Structure, Properties of Cobalt and Zinc Complexes Based on N,N’-Diisobutyl-2,3-diaminoquinoxaline[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1160-1166. doi: 10.11862/CJIC.2014.176 shu

Syntheses, Crystal Structure, Properties of Cobalt and Zinc Complexes Based on N,N’-Diisobutyl-2,3-diaminoquinoxaline

1.
1 School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China;

Received Date: 18 July 2013
Available Online: 21 February 2014
Fund Project: 国家自然科学基金(No.21171075/BO10303，21103073/BO30201)；江苏省研究生创新项目(No.cxzz13_0679)以及国家博士后科学基金(No.2013T60500)资助项目。 (No.21171075/BO10303，21103073/BO30201)；江苏省研究生创新项目(No.cxzz13_0679)以及国家博士后科学基金(No.2013T60500)

N,N'-Diisobutyl-2,3-diaminoquinoxaline was synthesized by 2,3-dichloroquinoxaline and isobutylamine. And the complexes ([Co(DIDAQX)Cl₂]) (1, DIDAQX=N,N'-Diisobutyl-2,3(1H,4H)-diaminoquinoxaline) and ([Zn(DIDAQX)Cl₂]) (2) (Same revision as above)were prepared, which characterized by elemental analysis, IR spectra, single crystal X-ray diffraction, TGanalysis, fluorescence and electrochemical properties. For 1, DFT and TD-DFT calculations have been performed to obtain its UV-Vis absorption spectrum, and a satisfactory theoretical-experimental agreement was achieved. The crystal structures of complexes 1 and 2 show that they crystallize in orthorhombic space group Pbca with a=1.4082(3) nm, b=1.4628(3) nm, c=1.7970(4) nm; V= 3.7017(14) nm³, Z=8 of 1 and a=1.4082(3) nm, b=1.4648(3) nm, c=1.7969(4) nm; V=3.7065(14) nm³, Z=8 of 2. In the structure of complexes, each metal atom is four coordinated. Besides chelated by the DIDAQX with two nitrogen atoms, the atom is also coordinated by two Cl atoms, thus form a distorted tetrahedral geometry.
- Cobalt(Ⅱ) complex;Zinc(Ⅱ) complex;crystal structure;property;density functional theory
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沈阳化工大学材料科学与工程学院沈阳 110142