Citation: DONG Li-Jun, LIU Yao, JI Xue-Mei, WEI Ya-Bo, XU Qing-Hong. Effect of Metal Ion on Conversion from M2+/Fe2+/Fe3+/LDHs to Spinel Ferrites under Mild Conditions[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1119-1127. doi: 10.11862/CJIC.2014.172
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The Effect of divalent metal ion was studied on conversion of M2+/Fe2+/Fe3+-LDHs (M=Co, Ni, Mn, Zn) to spinel ferrites under mild conditions (below 100 ℃ in open air). The results show that the conversion is not only affected by aging temperature but also by position of M2+ in periodic table of elements. Large radius of M2+ ions will result in much easier formation of spinel ferrites from LDH microcrystallines when these ions are in the same period and close to each other. Also the existence of Fe2+ plays an important role in the process, and the conversion could not happen without participation of Fe2+ under the conditions studied.
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