Citation: YU Jiang-Xi, FENG Yong-Lan, PENG Yan, JIANG Wu-Jiu, ZHU Xiao-Ming, KUANG Dai-Zhi, ZHANG Fu-Xing, WANG Jian-Qiu, YU Jun-Jie. Synthesis, Characterization, Quantum Chemistry, Thermal and Fluorescence Property of a Ladderlike Tetranuclear Organooxotin Cluster[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1135-1142. doi: 10.11862/CJIC.2014.152 shu

Synthesis, Characterization, Quantum Chemistry, Thermal and Fluorescence Property of a Ladderlike Tetranuclear Organooxotin Cluster

1.
Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Received Date: 15 May 2013
Available Online: 15 November 2013
Fund Project: 湖南省自然科学基金(No.13JJ3112)；湖南省科技计划(No.2013TZ2025)；湖南省高校创新平台开放基金(No.12K124) (No.13JJ3112)；湖南省科技计划(No.2013TZ2025)；湖南省高校创新平台开放基金(No.12K124)教育厅一般项目(No.12C0537)；湖南省普通高校功能金属有机材料重点实验室开放基金(No.10K02)；衡阳市科技计划(No.2011KG56，2012KJ30)；衡阳师范学院青年骨干教师培养计划(2012)资助项目。 (No.12C0537)；湖南省普通高校功能金属有机材料重点实验室开放基金(No.10K02)；衡阳市科技计划(No.2011KG56，2012KJ30)；衡阳师范学院青年骨干教师培养计划(2012)

An organooxotin cluster [(μ-O)(μ-OMe)(L)Sn₂(CH₂Ph)₄]₂ (HL=(MeO)₂C₆H₃CO₂H) has been synthesized by the dealkylation reaction of (PhCH₂)₃SnCl with 3,4-dimethoxybenzoic acid in methanol, and was characterized by UV, IR, elemental analysis and X-ray crystal diffraction. The crystal belongs to triclinic system, space group P1 with the cell parameters: a=1.2256(5) nm, b=1.2294(5) nm, c=1.3780(5) nm, α=69.784(7)°, β=68.568(7)°, γ=72.926(7)°, V=1.7801(12) nm³, Z=1, D_c=1.549 g·cm^-3, μ(MoKα)=1.447 mm^-1, F(000)=832, R₁=0.0261 and wR₂=0.0606. Crystal structure shows a distorted trigonal bipyramidal configuration with five-coordination for the central tin atom, and the complex has a centrosymmetric structure mode with a four-membered central endocyclic Sn₂O₂ unit. Due to the C-H…π interactions between phenyl-Hand benzene ring, the adjacent molecules of the complex is linked to generate 1D ribbon structure. Atheoretical investigation of one structural unit of the title complex was carried out using Gaussian 03W at LANL2DZ level. The stability and the composition of the frontier molecular orbitals confirmed the coordination geometry of the crystal structure. Thermogravimetric analysis shows that the complex is stable up to 128 ℃. Moreover, its fluorescence spectra was also investigated.
- organooxotin cluster;synthesis;crystal structure;quantum chemistry;thermal stability
1. [1]
  [1] Yabe Y, Maegawa T, Monguchi Y, et al. Tetrahedron, 2010, 66:8654-8660
2. [2]
  [2] Majumdar K C, Chattopadhyay S K. Tetrahedron Letters, 2004, 45:6871-6873
3. [3]
  [3] LÜ Yan(吕妍), LAN Zhi-Li(兰支利), LI Jing(李靖), et al. Chem. J. Chinese Universities(高等学校化学学报), 2002, 23 (5): 849-851
4. [4]
  [4] Schreiber S L, Meyers H V. J. Am. Chem. Soc., 1988, 110 (15):5198-5200
5. [5]
  [5] Davies A G, Gielen M, Pannell K H, et al. Tin Chemistry: Fundamentals, Frontiers, and Applications. Chichester: John Wiley & Sons Ltd, 2008:313
6. [6]
  [6] Abbas S, Hussain M, Ali S, et al. J. Organomet. Chem., 2013, 724:255-261
7. [7]
  [7] Ahmad S, Knowles C O. Comp. Gen. Pharmac., 1972, 3:125-133
8. [8]
  [8] Lecat J L, Devaud M. J. Organomet. Chem., 1983, 244:217-224
9. [9]
  [9] TIAN Lai-Jin(田来进), SUN Yu-Xi(孙玉希), ZHENG Xiao-Liang(郑晓亮), et al. Chinese J. Inorg. Chem.(无机化学学报), 2006, 22(4):629-632
10. [10]
  [10] Kang W, Wu X, Huang J. J. Organomet. Chem., 2009, 694: 2402-2408
11. [11]
  [11] Švec P, Padělková Z, RČžiČka A, et al. J. Organomet. Chem., 2011, 696:676-686
12. [12]
  [12] Chandrasekhar V, Schmid C G, Burton S D, et al. Inorg. Chem., 1987, 26(7):1050-1056
13. [13]
  [13] Gielen M, Meunier-Piret J, Biesemans M, et al. Appl. Organomet. Chem., 1992, 6, 59-67
14. [14]
  [14] Swamy K C K, Day R O, Holmes R R. J. Am. Chem. Soc., 1987, 109(18):5546-5548
15. [15]
  [15] Ruan B, Tian Y, Zhou H, et al. Inorg. Chim. Acta, 2011, 365:302-308
16. [16]
  [16] Eychenne-Baron C, Ribot F, Steunou N, et al. Organometallics, 2000, 19(10):1940-1949
17. [17]
  [17] Chandrasekhar V, Thilagar P, Bickley J F, et al. J. Am. Chem. Soc., 2005, 127(33):11556-11557
18. [18]
  [18] Swamy K C K, Day R O, Holmes R R. Inorg. Chem., 1992, 31(20):4184-4193
19. [19]
  [19] Swamy K C K, Schmid C G, Day R O, et al. J. Am. Chem. Soc., 1988, 110(21):7067-7076
20. [20]
  [20] Holmes R R, Swamy K C K, Schmid C G, et al. J. Am. Chem. Soc., 1988, 110(21):7060-7066
21. [21]
  [21] ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), WANG Jian-Qiu(王剑秋), et al. Chinese J. Org. Chem. (有机化学), 2008, 28(8):1457-1461
22. [22]
  [22] KUANG Dai-Zhi(邝代治), FENG Yong-Lan(冯泳兰), ZHANG Fu-Xing(张复兴), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010, 26(12):2160-2164
23. [23]
  [23] DENG Yi-Feng(邓弈芳), CHEN Man-Sheng(陈满生), ZHANG Chun-Hua(张春华), et al. Chinese J. Inorg. Chem. (无机化学学报), 2009, 25(12):2229-2232
24. [24]
  [24] ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), FENG Yong-Lan(冯泳兰), et al. Chinese J. Org. Chem.(有机化学), 2003, 23(4):368-371
25. [25]
  [25] KE Yi-Kan(柯以侃), DONG Hui-Ru(董慧茹). Analysis Chemistry Handbook: Vol.3(分析化学手册: 第三分册). Beijing: Chemical Industry Press, 1998:932, 935
26. [26]
  [26] XIE Qing-Lan(谢庆兰), XU Xiao-Hua(徐效华), ZHANG Dian-Kun(张殿坤), et al. Acta Chim. Sinica(化学学报), 1992, 50(5):508-514
27. [27]
  [27] Dokorou V, Demertzis M A, Jasinski J P, et al. J. Organomet. Chem., 2004, 689:317-325
28. [28]
  [28] Kovala-Demertzi D, Dokorou V, Kruszynski R, et al. Z. Anorg. Allg. Chem., 2005, 631:2481-2484
29. [29]
  [29] Wu X, Kang W, Zhu D, et al. J. Organomet. Chem., 2009, 694:2981-2986
30. [30]
  [30] LUO Hui-Ping(罗惠萍), WANG Yi-Xing(王逸兴), LIN Ze-Chen(林泽琛), et al. Four Spectra Fundamentals of Organic Chemistry(有机化学四谱基础). Hangzhou: Zhejiang University Press, 1988:17
31. [31]
  [31] XU Jin-Gou(许金钩), WANG Zun-Ben(王尊本). Fluorescence Analysis. 3rd Edition(荧光分析法). Beijing: Science Press, 2006:26-27
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
8. [8]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
9. [9]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
10. [10]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
11. [11]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
12. [12]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
13. [13]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
14. [14]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
15. [15]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
16. [16]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
17. [17]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
18. [18]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
19. [19]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
20. [20]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(268)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142