Citation: HU Yun-Xia, ZHANG Wen-Wei, LI Yi-Zhi, BAI Jun-Feng. Synthesis, Crystal Structures and Properties of Cadmium Coordination Polymers Based on 2-Aminoterephthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 717-724. doi: 10.11862/CJIC.2014.149 shu

Synthesis, Crystal Structures and Properties of Cadmium Coordination Polymers Based on 2-Aminoterephthalic Acid

HU Yun-Xia ^1,2 ,
ZHANG Wen-Wei ^1,, ,
LI Yi-Zhi ¹ ,
BAI Jun-Feng ^1,,

1.
1 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;

Corresponding author: ZHANG Wen-Wei, BAI Jun-Feng,
Received Date: 29 May 2013
Available Online: 10 January 2014
Fund Project: 国家自然科学基金(No.20771058)；教育部博士点基金(No.200802840011)；新疆凝聚态相变与微结构实验室开放课题基金(No.XJDX0912-2011-01)资助项目。 (No.20771058)；教育部博士点基金(No.200802840011)；新疆凝聚态相变与微结构实验室开放课题基金(No.XJDX0912-2011-01)

Three cadmium coordination polymers, named as [Cd(AT)(H₂O)]_n (1), [Cd(AT)(Py)]_n (2) and [Cd(AT)(BPP)]_n (3) (AT=2-aminoterephthalate, Py=pyridine, BPP=1,3-bi(pyridin-4-yl)propane), have been synthesized based on₂-aminoterephthalic acid. The crystal structures indicate that 2-aminoterephthalate exhibits three different coordination modes in these compounds due to different auxiliary ligands, resulting in rtl (1), ths (2) and sql (3) topology, respectively. They display good thermal stability due to intermolecular/intramolecular hydrogen bonding, π…π stacking and C-H…π interactions within the framework.
- 2-aminoterephthalic acid;solvothermal synthesis;crystal structure;coordination polymer
1. [1]
  [1] Zaworotko M J. Nature Chemistry, 2009, 1:267-268
2. [2]
  [2] Zaworotko M J. Nature, 2008, 451:410-411
3. [3]
  [3] Ma S, Sun D, Yuan D, et al. J. Am. Chem. Soc., 2009, 131: 6445-6451
4. [4]
  [4] Férey G, Mellot-Draznieks C, Serre C, et al. Science, 2005, 309:2040-2042
5. [5]
  [5] Zhang J P, Chen X M. J. Am. Chem. Soc., 2008, 130:6010-6017
6. [6]
  [6] Wanderley M M, Wang C, Wu C D, et al. J. Am. Chem. Soc., 2012, 134:9050-9053
7. [7]
  [7] Das M C, Guo Q, He Y B, et al. J. Am. Chem. Soc., 2012, 134:8703-8710
8. [8]
  [8] Poloni R, Smit B, Neaton J B. J. Am. Chem. Soc., 2012, 134: 6714-6719
9. [9]
  [9] Eubank J F, Wojtas L, Hight M R, et al. J. Am. Chem. Soc., 2011, 133:17532-17535
10. [10]
  [10] Wang C, Xie Z G, deKrafft K E, et al. J. Am. Chem. Soc., 2011, 133:3445-13454
11. [11]
  [11] Wang S N, Sun R, Wang X S, et al. CrystEngComm, 2007, 9:1051-1061
12. [12]
  [12] Sun R, Li Y Z, Bai J F, et al. Cryst. Growth Des., 2007, 7: 890-894
13. [13]
  [13] Wang L F, Kang L C, Zhang W W, et al. Dalton Trans., 2011, 40:9490-9497
14. [14]
  [14] Hu Y X, Wang L F, Zhang W W, et al. Inorg. Chem. Commun., 2012, 17:173-176
15. [15]
  [15] Hu Y X, Ma H B, Zheng B, et al. Inorg. Chem., 2012, 51: 7066-7074
16. [16]
  [16] Eddaoudi M, Kim J, Rosi N, et al. Science, 2002, 295:469-472
17. [17]
  [17] Hao H J, Sun D, Li Y H, et al. Cryst. Growth Des., 2011, 11:3564-3578
18. [18]
  [18] Amghouz Z, Roces L, Garcia-Granda S, et al. Inorg. Chem., 2010, 49:7917-7926
19. [19]
  [19] Ladrak T, Smulders S, Roubeau O, et al. Eur. J. Inorg. Chem., 2010, 24:3804-3812
20. [20]
  [20] Guillerm V, Gross S, Serre C, et al. Chem. Commun., 2010, 46:767-769
21. [21]
  [21] Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement; University of Göttingen: Göttingen, Germany, 1997.
22. [22]
  [22] Janiak C. J. Chem. Soc., Dalton Trans., 2000, 21:3885-3896
23. [23]
  [23] Zhang K L, Gao H Y, Pan Z C, et al. Polyhedron, 2007, 26: 5177-5184
24. [24]
  [24] Hao X R, Wang X L, Su Z M, et al. Dalton Trans., 2009: 8562-8566
25. [25]
  [25] Wang X F, Zhang Y B, Lin Y Y. CrystEngComm, 2013, 15: 3470-3477
1. [1]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
2. [2]
  Botao QU , Qian WANG , Qian WANG , Ruiping ZHANG . Synthesis, crystal structures, and luminescence properties of zinc coordination polymers based on 2,5-dibromoterephthalate. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 917-924. doi: 10.11862/CJIC.20260357
3. [3]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
4. [4]
  Jinyang SUI , Zhonghao NIU , Hao XU , Jingli XIE . Zinc(Ⅱ) coordination polymers from mixed triazole and carboxylate ligands: Synthesis and properties for CO₂ cycloaddition and photocatalytic dye degradation. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1603-1612. doi: 10.11862/CJIC.20260089
5. [5]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
6. [6]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
7. [7]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
8. [8]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
9. [9]
  Kaimin WANG , Na HE , Shiyi LI , Xuling BAI , Weiqing SUN , Yanqing YE , Yulu MA . Synthesis, Hirshfeld surface analysis and properties of two Zn(Ⅱ)/Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 55-64. doi: 10.11862/CJIC.20250178
10. [10]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
11. [11]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
12. [12]
  Longfei MA , Fang SI , Congjie PAN , Xinhua WANG . Synthesis and crystal structure of extended tetrathiafulvalene derivatives and cupric bromide charge transfer complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1229-1236. doi: 10.11862/CJIC.20250355
13. [13]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
14. [14]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
15. [15]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
16. [16]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
17. [17]
  Chengyan XU , Jiangnan YU , Yu LI , Xizhen PAN , Yinlin HOU , Wenmin WANG . Synthesis, structure, and bioactivity of a Ho₄ complex bridged by azide group. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1453-1462. doi: 10.11862/CJIC.20260033
18. [18]
  Wenjuan SHI , Yuxuan LEI , Lei HOU , Yaoyu WANG . Synthesis, structure, and luminescence properties of trinucluear Cu(Ⅰ)-pyrazole complexes containing different substituent groups. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 543-550. doi: 10.11862/CJIC.20250270
19. [19]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
20. [20]
  Xiaoqi LAN , Wei LI , Long JING , Mengyu SU , Xiaoling LUO , Zheng LIU , Qun TANG . Synthesis, crystal structure, and spectral properties of transition-metal-organic frameworks based on thiophene carboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 309-316. doi: 10.11862/CJIC.20250212

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1894)
HTML views(317)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142