Citation: HU Yun-Xia, ZHANG Wen-Wei, LI Yi-Zhi, BAI Jun-Feng. Synthesis, Crystal Structures and Properties of Cadmium Coordination Polymers Based on 2-Aminoterephthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 717-724. doi: 10.11862/CJIC.2014.149 shu

Synthesis, Crystal Structures and Properties of Cadmium Coordination Polymers Based on 2-Aminoterephthalic Acid

HU Yun-Xia ^1,2 ,
ZHANG Wen-Wei ^1,, ,
LI Yi-Zhi ¹ ,
BAI Jun-Feng ^1,,

1.
1 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;

Corresponding author: ZHANG Wen-Wei, BAI Jun-Feng,
Received Date: 29 May 2013
Available Online: 10 January 2014
Fund Project: 国家自然科学基金(No.20771058)；教育部博士点基金(No.200802840011)；新疆凝聚态相变与微结构实验室开放课题基金(No.XJDX0912-2011-01)资助项目。 (No.20771058)；教育部博士点基金(No.200802840011)；新疆凝聚态相变与微结构实验室开放课题基金(No.XJDX0912-2011-01)

Three cadmium coordination polymers, named as [Cd(AT)(H₂O)]_n (1), [Cd(AT)(Py)]_n (2) and [Cd(AT)(BPP)]_n (3) (AT=2-aminoterephthalate, Py=pyridine, BPP=1,3-bi(pyridin-4-yl)propane), have been synthesized based on₂-aminoterephthalic acid. The crystal structures indicate that 2-aminoterephthalate exhibits three different coordination modes in these compounds due to different auxiliary ligands, resulting in rtl (1), ths (2) and sql (3) topology, respectively. They display good thermal stability due to intermolecular/intramolecular hydrogen bonding, π…π stacking and C-H…π interactions within the framework.
- 2-aminoterephthalic acid;solvothermal synthesis;crystal structure;coordination polymer
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