Citation: CHU Zhao-Jing, BAI Xiao-Guang, WANG Yu-Cheng, CHEN Jin-Mei, ZHAO Hong. Crystal, Structures of, Cobalt(Ⅱ) and, Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 945-951. doi: 10.11862/CJIC.2014.148
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Two compounds CoCl4(Athpp)2·2H2O (1) and CuCl4(Athpp)2 (2) were respectively obtained by the reactions of 3-amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole (Athpp) with cobalt(Ⅱ) chlorine and copper(Ⅱ) chlorine. The compounds have been characterized by FT-IR, elemental analyses and crystal structures. The compound 1 crystallizes in P1 space group and the compound 2 crystallizes in P21/n space group. The central metals are adopt distorted octahedral geometry. In addition, the fluorescent spectroscopy of the compounds were studied in solid state at room temperature.
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