Citation: ZHANG Chun-Li, QIN Ling, ZHENG He-Gen. Synthesis, Crystal Structure and Optical Properties of Zinc Coordination Polymer from 5-Aminonicotinic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 800-804. doi: 10.11862/CJIC.2014.143 shu

Synthesis, Crystal Structure and Optical Properties of Zinc Coordination Polymer from 5-Aminonicotinic Acid Ligand

1.
1 School of Biological and Chemical Engineering, Suzhou University; Anhui Key Laboratory of Spin Electron and Nanomaterials, Suzhou University, Suzhou, Anhui 234000, China;

Corresponding author: ZHENG He-Gen,
Received Date: 28 August 2013
Available Online: 4 December 2013
Fund Project: 国家重点基础研究发展计划(2010CB923303)；国家自然科学基金(No.91022011)资助项目。 (2010CB923303)；国家自然科学基金(No.91022011)

A 2Dcoordination polymer [Zn(5-ana)₂]_n(1), based on a rigid ligand 5-ana(5-anaH=5-aminonicotinic acid)has been synthesized by hydrothermal method and characterized by elemental analysis, IR spectra, TGA, XRD, and the crystal structure was determined by single-crystal X-ray diffraction. The coordination polymer crystallizes in the orthorhombic system, space group P2₁2₁2₁, and features 2D layer structure. Second harmonic generation efficiency and fluorescence of the coordination polymer are also further investigated. The results show that this coordination polymer has a second harmonic generation, which can be used as a second-order nonlinear optical material. Fluorescence of the coordination polymer exhibits a blue shift compared with free ligand.
- Zn(Ⅱ) coordination polymer;crystal structure;optical properties
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沈阳化工大学材料科学与工程学院沈阳 110142