Citation: ZHANG Chun-Li, QIN Ling, ZHENG He-Gen. Synthesis, Crystal Structure and Optical Properties of Zinc Coordination Polymer from 5-Aminonicotinic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 800-804. doi: 10.11862/CJIC.2014.143
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A 2Dcoordination polymer [Zn(5-ana)2]n(1), based on a rigid ligand 5-ana(5-anaH=5-aminonicotinic acid)has been synthesized by hydrothermal method and characterized by elemental analysis, IR spectra, TGA, XRD, and the crystal structure was determined by single-crystal X-ray diffraction. The coordination polymer crystallizes in the orthorhombic system, space group P212121, and features 2D layer structure. Second harmonic generation efficiency and fluorescence of the coordination polymer are also further investigated. The results show that this coordination polymer has a second harmonic generation, which can be used as a second-order nonlinear optical material. Fluorescence of the coordination polymer exhibits a blue shift compared with free ligand.
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