Citation: LIU Xi-Hui, ZHUO Xin, LIU Chao, LIU Tai-Zhu. Synthesis and Crystal Structure of Two 3D Networks Ni(Ⅱ)/Co(Ⅱ) Coordination Complexes Based on Bipyridine and Methanoic acid[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1128-1134. doi: 10.11862/CJIC.2014.142 shu

Synthesis and Crystal Structure of Two 3D Networks Ni(Ⅱ)/Co(Ⅱ) Coordination Complexes Based on Bipyridine and Methanoic acid

LIU Xi-Hui ^1,2 ,
ZHUO Xin ² ,
LIU Chao ² ,
LIU Tai-Zhu ²

1.
1 School of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China;

Received Date: 30 April 2013
Available Online: 2 December 2013
Fund Project: 安徽省教育厅自然科学基金项目(No.KJ2011Z369，KJ2012A268，KJ2013A247)；安徽省优秀青年基金项目(No.2012SQRL207)；自旋电子与纳米材料安徽省重点实验室开放课题(No.2013YKF23，2011YKF02) (No.KJ2011Z369，KJ2012A268，KJ2013A247)；安徽省优秀青年基金项目(No.2012SQRL207)；自旋电子与纳米材料安徽省重点实验室开放课题(No.2013YKF23，2011YKF02)宿州学院纳米功能材料及应用创新团队(No.2013KYTD02)资助项目。 (No.2013KYTD02)

Two transition metal complexes, [M(bipy)(Metha)₂]_n·nH₂O (M=Ni, 1; Co, 2; bipy=4,4'-bipyridine, Metha=methanoic acid), have been synthesized by hydrothermal synthesis and characterized by elemental analyses, IR spectroscopy, and X-ray single-crystal diffraction etc. The single crystal structures show the two complexes belong to monoclinic system, C2/c space group. Complexes 1 and 2 have similar 3Dnetwork structures. Metha have two kinds of different types with M²⁺ ion, one kind is the two oxygen atoms of the Metha as bridging ligand atoms, connected by chain with bipy, another is the carboxyl oxygen of the Metha with only one oxygen atom with another M²⁺ ion.
- crystal structure;coordination complex;network structure
1. [1]
  [1] Shigematsu A, Yamada T, Kitagawa H. J. Am. Chem. Soc., 2012, 134(32):13145-3147
2. [2]
  [2] Das M C, Guo Q S, He Y B, et al. J. Am. Chem. Soc., 2012, 134(20):8703-8710
3. [3]
  [3] Fang C, Liu Q K, Ma J P, et al. Inorg. Chem., 2012, 51(7): 3923-3925
4. [4]
  [4] Sengupta O, Gole B, Mukherjee P S. Polyhedron, 2010, 29 (15):2945-2952
5. [5]
  [5] GUAN Lei(关磊), WANG Ying(王莹), LÜ Shan(吕山), et al. Chinese J. Inorg. Chem. (无机化学学报), 2013, 10, (29): 2079-2084
6. [6]
  [6] Liu T F, Lü J, Tian C B, et al. Inorg. Chem., 2011, 50(6): 2264-2271
7. [7]
  [7] Horike S, Dincǎ M, Tamaki K, et al. J. Am. Chem. Soc., 2008, 130(18):5854-5855
8. [8]
  [8] Huang Y B, Liu T F, Lin J X, et al. Inorg. Chem., 2011, 50 (6):2191-2198
9. [9]
  [9] Kushch N D, Yagubskii E B, Kartsovnik M V, et al. J. Am. Chem. Soc., 2008, 130(23):7238-7240
10. [10]
  [10] Lu G, Hupp J T. J. Am. Chem. Soc., 2010, 132(23):7832-7833
11. [11]
  [11] Jiang H L, Feng D W, Liu T F, et al. J. Am. Chem. Soc., 2012, 134(36):14690-14693
12. [12]
  [12] Wu H, Ma J F, Liu Y Y, et al. CrystEngComm, 2011, 13(23): 7121-7128
13. [13]
  [13] Yuan D Q, Zhao D, Sun D F, et al. Angew. Chem. Int. Ed., 2010, 49(31):5357-5361
14. [14]
  [14] Pachfule P, Dey C, Panda T, et al. Cryst. Growth Des., 2010, 10(3):1351-1363
15. [15]
  [15] Sarma R, Kalita D, Baruah J B. Dalton Trans., 2009, 36: 7428-7436
16. [16]
  [16] Hu J S, Huang L F, Yao X Q, et al. Inorg. Chem., 2011, 50 (6):2404-2414
17. [17]
  [17] Pachfule P, Das R, Poddar P, et al. Inorg. Chem., 2011, 50 (9):3855-3865
18. [18]
  [18] Yao X Q, Cao D P, Hu J S, et al. Cryst. Growth Des., 2011, 11(1):231-239
19. [19]
  [19] Ni J, Wei K J, Liu Y Z, et al. Cryst. Growth Des., 2010, 10 (9):3964-3976
20. [20]
  [20] Kanoo P, Gurunatha K L, Maji T K. Cryst. Growth Des., 2009, 9(9):4147-4156
21. [21]
  [21] Hu J S, Shang Y J, Yao X Q, et al. Cryst. Growth Des., 2010, 10(9):4135-4142
22. [22]
  [22] Duan X Y, Cheng X, Lin J G, et al. CrystEngComm, 2008, 10(6):706-714
23. [23]
  [23] Zang S Q, Su Y, Song Y, et al. Cryst. Growth Des., 2006, (6) 10:2369-2375
24. [24]
  [24] Chen S S, Fan J, Okamura T A, et al. Cryst. Growth Des., 2010, 10(2):812-822
25. [25]
  [25] Park H J, Cheon Y E, Suh M P. Chem. Eur. J., 2010, 16(38): 11662-11669
26. [26]
  [26] Hu J S, Yao X Q, Zhang M D, et al. Cryst. Growth Des., 2012, 12(7):3426-3435
27. [27]
  [27] Chen X L, Wu Q R, Hu H M, et al. Inorg. Chim. Acta, 2010, 363(2):360-367
28. [28]
  [28] Boeckmann J, Wriedt M, Nather C. Eur. J. Inorg. Chem., 2010, 2010(12):1820-1828
29. [29]
  [29] Fu Y L, Xu Z W, Ren J L, et al. Acta Crystallogr., Sect. E: Struct. Rep. Online, 2005, 61(10):m1897-m1899
30. [30]
  [30] QIU Wen-Ge(邱文革), DENG Fang(邓芳), LIU Hu-Bing (刘虎冰), et al. Chinese J. Inorg. Chem. (无机化学学报), 2013, 10(29):2021-2026
31. [31]
  [31] HU Jiu-Rong(胡久荣), YAN Wei-Hong(闫卫红), ZHENG Da-Gui(郑大贵), et al. Chinese J. Inorg. Chem. (无机化学学报), 2012, 3(28):531-535
32. [32]
  [32] Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Göttinggen, Göttinggen, Germany, 1997.
33. [33]
  [33] Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttinggen, Göttinggen, Germany, 1997.
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