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Citation: TONG Bi-Hai, LIU Yuan-Yuan, ZHANG Man, MEI Qun-Bo, HUA Zhong-Sheng, ZHANG Qiang-Feng. Synthesis and Properties of a Series of Ruthenium(Ⅱ) Complexes with 4,5-Diaza-9,9’-spirobifluorene Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1174-1178. doi: 10.11862/CJIC.2014.141 shu

Synthesis and Properties of a Series of Ruthenium(Ⅱ) Complexes with 4,5-Diaza-9,9’-spirobifluorene Ligands

  • 1.

    1 College of Metallurgy and Resources, Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma'anshan, Anhui 243002, China;

  • Received Date: 5 September 2013
    Available Online: 22 November 2013

    Fund Project: 国家自然科学基金(No.50903001，51204002) (No.50903001，51204002)安徽高校自然科学研究项目(No.KJ2013A063)资助项目。 (No.KJ2013A063)

  • Three ruthenium complexes, [Ru(bpy)2(SB)](PF6)2, [Ru(bpy)(SB)2](PF6)2 and [Ru(SB)3](PF6)2 (bpy=2,2'-bipyridine, SB=4,5-diaza-9,9'-spirobifluorene), have been synthesized and characterized. [Ru(bpy)2(SB)](PF6)2 has also been characterized by single-crystal X-ray diffraction. Its crystal belongs to orthorhombic system with Pbca space group, in which a=1.8818(2) nm, b=1.9913(3) nm, c=2.4221(3) nm, Z=8. The photophysical properties of these complexes were investigated. [Ru(bpy)2(SB)](PF6)2 shows orange red emission at around 606 nm with a phosphorescence quantum yield of ca. 0.0012, while [Ru(bpy)(SB)2](PF6)2 and [Ru(SB)3](PF6)2 shows rather weak or almolst no emissiom at the same condition. The electrochemiluminescence performance of these complexes has also be studied. With the increase of SB ligand concentration, the peak potential increased from 1.36 Vto 1.58 V, and relative peak intensity decreased from 731 to 52.
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