Citation: XUE Jian-Lei, TIAN Chun-Hua. Lead(Ⅱ) Coordination Polymer with 4-Chlorophenoxyacetate as Ligand：Structure, Luminescence and Biological Bctivity[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 907-912. doi: 10.11862/CJIC.2014.140 shu

Lead(Ⅱ) Coordination Polymer with 4-Chlorophenoxyacetate as Ligand：Structure, Luminescence and Biological Bctivity

XUE Jian-Lei ,
TIAN Chun-Hua ^,

1.
Medical Technology Department, Qiqihar University, Qiqihar, Heilongjiang 161006, China

Corresponding author: TIAN Chun-Hua,
Received Date: 11 July 2013
Available Online: 21 November 2013
Fund Project: 黑龙江省教育厅科学技术研究基金(No.12521640,12531833)资助项目。 (No.12521640,12531833)

Anew 1D lead(Ⅱ) coordination polymer, [Pb(4-cpa)₂(H₂O)]_n (1, 4-cpa=4-chlorophenylacetate), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy, TGA, powder X-ray diffraction and single crystal X-ray diffraction. Structural determination reveals that 1 exhibits an interesting 1D chain structure constructed by 4-cpa ligands. Solid-state 1 emits the intensely blue photoluminescence with fluorescence lifetime of 5.3 ns (422 nm) at room temperature. The 4-Hcpa ligand and complex 1 have been screened for their phytogrowth-inhibitory activities against Brassica napus L. and Echinochloa crusgalli L., and the results are compared with the activity of quizalofop-p-ethyl.
- lead(Ⅱ) coordination polymer;hydrothermal synthesis, crystal structure, luminescence, biological activity
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沈阳化工大学材料科学与工程学院沈阳 110142