Citation: XUE Jian-Lei, TIAN Chun-Hua. Lead(Ⅱ) Coordination Polymer with 4-Chlorophenoxyacetate as Ligand:Structure, Luminescence and Biological Bctivity[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 907-912. doi: 10.11862/CJIC.2014.140
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Anew 1D lead(Ⅱ) coordination polymer, [Pb(4-cpa)2(H2O)]n (1, 4-cpa=4-chlorophenylacetate), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy, TGA, powder X-ray diffraction and single crystal X-ray diffraction. Structural determination reveals that 1 exhibits an interesting 1D chain structure constructed by 4-cpa ligands. Solid-state 1 emits the intensely blue photoluminescence with fluorescence lifetime of 5.3 ns (422 nm) at room temperature. The 4-Hcpa ligand and complex 1 have been screened for their phytogrowth-inhibitory activities against Brassica napus L. and Echinochloa crusgalli L., and the results are compared with the activity of quizalofop-p-ethyl.
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