Citation: ZHANG Qi-Long, FENG Guang-Wei, WANG Li, WANG Zheng, ZHU Bi-Xue. Synthesis, Crystal Structure and Antibacterial Activity of Schiff Base Ni(Ⅱ) Complexes Containing Schiff Base and Imidazole[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1025-1030. doi: 10.11862/CJIC.2014.130
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The two nickel (Ⅱ) complexes [Ni(L)(Himdz)](1)、[Ni(L)(Mimdz)](2) were synthesized from the reaction of tridentate Schiff base (1-phenyl-3-[(2-hydroxyphenyl)imino]-1-butanone) (H2L) and monodentate N-heterocycles [imidazole (Himdz), 2-methylimidazole (Mimdz)] with Ni(OAc)2·4H2O and characterized by elemental analysis, IR, 1H NMR spectroscopy. An X-ray structure determination of the complexes has been completed. In the solid state, both [Ni(L)(Himdz)] (1), [Ni(L)(Mimdz)] (2) crystallize in P21/c space groups, and exist as dimers due to intermolecular C-H…π interactions. Each of the dimeric molecules forms a one-dimensional zigzag chain via intermolecular N-H…O hydrogen bonds involving the heterocycle N-H group, respectively. The antibacterial activities of the ligand and complexes were tested against seven kinds of bacteria. The results show that the complexes 1 and 2 possess inhibiting effects.
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-
[1]
[1] Zhang Q L, Zhu B X, Zhang Y Q, et al. Cryst. Growth Des., 2011, 11, 5688-5695
-
[2]
[2] Arnold P L, Hollis E, Nichol G S, et al. J. Am. Chem. Soc., 2013, 135, 3841-3854
-
[3]
[3] ZHU Bi-Xue(朱必学), RUAN Wen-Juan(阮文娟), ZHU Zhi-Ang(朱志昂), et al. Acta Chim. Sinica (化学学报), 2004, 62 (1):58-65
-
[4]
[4] ZHU Bi-Xue(朱必学), RUAN Wen-Juan(阮文娟), ZHU Zhi-Ang(朱志昂), et al. Chinese J. Inorg. Chem. (无机化学学 报), 2005, 21(2):169-175
-
[5]
[5] HU Guo-Qiang(胡国强), HOU Li-Li(侯莉莉), XIE Song-Qiang(谢松强), et al. Chinese J. Org. Chem. (有机化学), 2008, 28(4):700-7041
-
[6]
[6] MENG Hua(孟华), XIE Zheng-Feng(解正峰), HU Jun(胡君), et al. Chinese J. Org. Chem. (有机化学), 2008, 28(8):1423-1427
-
[7]
[7] SUN Xiao-Hong(孙晓红), BAI Yan(白燕), LIU Yuan-Fa (刘源发), et al. Acta Chim. Sinica (化学学报), 2008, 68(8): 788-792
-
[8]
[8] LIANG Fang-Zhen(梁芳珍), DU Ming(杜鸣), REN Jian-Cheng(任建成). Chinese J. Inorg. Chem. (无机化学学报), 1999, 15(3):393-396
-
[9]
[9] Alexiou M, Tsivikas I, Dendrinou-Samara C, et al. J. Inorg. Biochem., 2003, 93:256
-
[10]
[10] JIA Wen-Ping(贾文平), YANG Jian-Guo(杨健国), LI Fang (李芳), et al. Chinese J. Inorg. Chem. (无机化学学报), 2008, 24(4):627-630.
-
[11]
[11] Sheldrick G M. SHELXL-97, University of Göttingen, Germany, 1997.
-
[1]
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