Citation: DONG Wen-Kui, ZHANG Xin-Ying, ZHAO Meng-Meng, LI Gang, DONG Xiu-Yan. Syntheses and Crystal Structures of 5-Methoxy-6’-hydroxy-2,2’-[ethylenedioxybis(nitrilomethylidyne)]diphenol and Its Tetranuclear Zinc(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 710-716. doi: 10.11862/CJIC.2014.120 shu

Syntheses and Crystal Structures of 5-Methoxy-6’-hydroxy-2,2’-[ethylenedioxybis(nitrilomethylidyne)]diphenol and Its Tetranuclear Zinc(Ⅱ) Complex

1.
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Received Date: 9 August 2013
Available Online: 13 November 2013
Fund Project: 国家自然科学基金(No.21361015) (No.21361015)甘肃省高校科技支撑基金(212086) (212086)兰州交通大学科技支撑基金(ZC2012003)资助项目。 (ZC2012003)

An asymmetrical Salamo-type ligand, 5-methoxy-6'-hydroxy-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol (H₃L), and its Zn(Ⅱ) complex, [Zn₄L₂(CH₃OH)₂(OAc)₂], have been synthesized and structurally characterized by X-ray diffraction methods. X-ray crystallographic analyses reveal that the ligand adopts a V-shaped configuration, in which the two benzene rings are approximately perpendicular, making a dihedral angle of 85.71(3)°; the Zn(Ⅱ) complex adopts two different kinds of coordination geometries: trigonal bipyramidal and square pyramidal geometries. Meanwhile, each Zn(Ⅱ) complex molecule links four other molecules to form an infinite 2D layer structure through intermolecular hydrogen bond interactions. CCDC: 954985, H₃L; 954984, Zn(Ⅱ) complex.
- asymmetrical salamo-type ligand;Zn(Ⅱ) complex;synthesis;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142