Citation: CHEN Yan-Min, XIE Qing-Fan. Synthesis and Crystal Structure of a 1D Chain-Like Cd(Ⅱ) Coordination Polymer Based on Dihydroxynaphthalenedisulfonate[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 517-521. doi: 10.11862/CJIC.2014.117
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A 1D cadmium(Ⅱ) coordination polymer, {[Cd2(dhns)(imdz)4]·H2O}n (1), was synthesized by reaction of disodium 3,6-dihydroxy-naphthalene-2,7-disulfonate (Na2H2dhns), imidazole (imdz) and Cd(NO3)2·4H2O in a water-methanol solution, and characterized by elemental analysis, IR, UV, PL, TG and single crystal X -ray diffraction. The complex crystallizes in the monoclinic system, space group C2/m, a=1.245 97(6) nm, b=1.558 33(9) nm, c=1.629 99(10) nm, β=90.258(6)°, V=3.164 8(3) nm3, Z=4, Mr=831.39, Dc=1.745 g·cm-3, μ=1.534 mm-1, F(000)=1 640, R=0.056 4, wR2=0.140 5, S=1.09. In 1, dhns4-ligands bridge two edge shared distorted octahedrons, in which Cd(Ⅱ) ions are in the center, forming 1D chains that are further connected by intermolecular hydrogen-bonding interactions, generating a 3D supramolecular network. CCDC: 939692.
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